Abstract. Daily global maps of monthly integrated UV-erythemal irradiance (290-400 nm) at the Earth's surface are estimated using the ozone amount, cloud transmittance, aerosol amounts, and surface reflectivity from the solar UV radiation backscattered from the Earth's atmosphere as measured by the total ozone mapping spectrometer (TOMS) and independently measured values of the extraterrestrial solar irradiance. The daily irradiance values at a given location show that short-term variability (daily to annual) in the amount of UV radiation, 290-400 nm, reaching the Earth's surface is caused by (1) partially reflecting cloud cover, (2) haze and absorbing aerosols (dust and smoke), and (3) ozone. The reductions of UV irradiance estimated from TOMS data can exceed 50 +_ 12% underneath the absorbing aerosol plumes in Africa and South America (desert dust and smoke from biomass burning) and exceeded 70 _ 12% during the Indonesian fires in September 1997 and again during March 1998. Recent biomass burning in Mexico and Guatemala have caused large smoke plumes extending into Canada with UV reductions of 50% in Mexico and 20% in Florida, Louisiana, and Texas. Where available, ground-based Sun photometer data show similar UV irradiance reductions caused by absorbing aerosol plumes of dust and smoke. Even though terrain height is a major factor in increasing the amount of UV exposure compared to sea level, the presence of prolonged clear-sky conditions can lead to UV exposures at sea level rivaling those at cloudier higher altitudes. In the equatorial regions, +_20 ø, the UV exposures during the March equinox are larger than during the September equinox because of increased cloudiness during September. Extended land areas with the largest erythemal exposure are in Australia and South Africa where there is a larger proportion of clear-sky days. The large short-term variations in ozone amount which occur at high latitudes in the range _+65 ø cause changes in UV irradiance comparable to clouds and aerosols for wavelengths between 280 nm and 300 nm that are strongly absorbed by ozone. The absolute accuracy of the TOMS monthly erythemal exposure estimates over a TOMS field of view is within +_6%, except under UV-absorbing aerosol plumes (dust and smoke) where the accuracy is within +_ 12%. The error caused by aerosols can be reduced if the height of the aerosol plume is more accurately known. The TOMS estimated irradiances are compared with ground-based Brewer spectroradiometer data obtained at Toronto, Canada. The Brewer irradiances are systematically 20% smaller than TOMS irradiance estimates during the summer months. An accounting of systematic errors brings the Brewer and TOMS irradiances into approximate agreement within the estimated instrumental uncertainties for both instruments. IntroductionThe global coverage afforded by satellite observations of UV irradiance, or flux density (energy per unit area per unit time), can be used to distinguish regional and global changes in contrast to purely local observations from grou...

We report observations and analysis of a pyro‐cumulonimbus event in the midst of a boreal forest fire blowup in Northwest Territories Canada, near Norman Wells, on 3–4 August 1998. We find that this blowup caused a five‐fold increase in lower stratospheric aerosol burden, as well as multiple reports of anomalous enhancements of tropospheric gases and aerosols across Europe 1 week later. Our observations come from solar occultation satellites (POAM III and SAGE II), nadir imagers (GOES, AVHRR, SeaWiFS, DMSP), TOMS, lidar, and backscattersonde. First, we provide a detailed analysis of the 3 August eruption of extreme pyro‐convection. This includes identifying the specific pyro‐cumulonimbus cells that caused the lower stratospheric aerosol injection, and a meteorological analysis. Next, we characterize the altitude, composition, and opacity of the post‐convection smoke plume on 4–7 August. Finally, the stratospheric impact of this injection is analyzed. Satellite images reveal two noteworthy pyro‐cumulonimbus phenomena: (1) an active‐convection cloud top containing enough smoke to visibly alter the reflectivity of the cloud anvil in the Upper Troposphere Lower Stratosphere (UTLS) and (2) a smoke plume, that endured for at least 2 hours, atop an anvil. The smoke pall deposited by the Norman Wells pyro‐convection was a very large, optically dense, UTLS‐level plume on 4 August that exhibited a mesoscale cyclonic circulation. An analysis of plume color/texture from SeaWiFS data, aerosol index, and brightness temperature establishes the extreme altitude and “pure” smoke composition of this unique plume. We show what we believe to be a first‐ever measurement of strongly enhanced ozone in the lower stratosphere mingled with smoke layers. We conclude that two to four extreme pyro‐thunderstorms near Norman Wells created a smoke injection of hemispheric scope that substantially increased stratospheric optical depth, transported aerosols 7 km above the tropopause (above ∼430 K potential temperature), and also perturbed lower stratospheric ozone.

Increases in ultraviolet fluxes (300 nm to 340 nm) reaching the ground between 1979 and 1992 are estimated using measured stratospheric ozone amounts and reflectivity data from Nimbus‐7/TOMS (Total Ozone Mapping Spectrometer). The UV‐increases are estimated from an ozone data set obtained using a new algorithm incorporating improved in‐flight instrument calibration. The 380 nm radiance data are used to show that there were no changes in ultraviolet atmospheric albedo due to clouds and aerosols from 1979 to 1992 within the 1% uncertainty of the measurements. Linear least squares fits to the monthly and annual increases in UV exposure since 1979 are given for 3 wavelengths (300 nm, 310 nm, and 320 nm) that are strongly, moderately, and weakly absorbed by ozone. The estimated linear changes for the 3 wavelengths become significant (2 standard deviations) poleward of about 40° latitude. In the 45°±5° latitude band, the slope of linear fits to the annual zonally averaged changes for these wavelengths are about 13%, 3%, and 1% per decade in the southern hemisphere, and 10%, 3%, and 1% per decade in the northern hemisphere. Similarly derived values are estimated for DNA, plant, and erythema action spectra. Monthly values of exposure changes are larger towards higher latitudes and during the spring and winter months (e.g., 8.6%, 9.8%, and 5.1% per decade during April at 45°N). Erythemal UV‐increases obtained from TOMS data disagree with previously determined ground based UV‐decreases from an average of 8 U.S. Robertson‐Berger sites.

The 1992 global average total ozone, measured by the Total Ozone Mapping Spectrometer (TOMS) on the Nimbus-7 satellite, was 2 to 3 percent lower than any earlier year observed by TOMS (1979 to 1991). Ozone amounts were low in a wide range of latitudes in both the Northern and Southern hemispheres, and the largest decreases were in the regions from 10 degrees S to 20 degrees S and 100N to 60 degrees N. Global ozone in 1992 is at least 1.5 percent lower than would be predicted by a statistical model that includes a linear trend and accounts for solar cycle variation and the quasi-biennial oscillation. These results are confirmed by comparisons with data from other ozone monitoring instruments: the SBUV/2 instrument on the NOAA-11 satellite, the TOMS instrument on the Russian Meteor-3 satellite, the World Standard Dobson Instrument 83, and a collection of 22 ground-based Dobson instruments.

On Monday, 19 July, and Tuesday, 20 July 2004, the air over Houston, Texas, appeared abnormally hazy. Transport model results and data from the Atmospheric Infrared Sounder (AIRS), the Moderate Resolution Imaging Spectrometer (MODIS), the Measurement of Ozone by Airbus In-service airCraft (MOZAIC) experiment, and the Total Ozone Mapping Spectrometer (TOMS) indicate that an air mass originating on 12 July 2004 over forest fires in eastern Alaska and western Canada arrived in Houston about 1 week later. Ozonesonde data from Houston on 19 and 20 July show elevated ozone at the surface (>125 ppbv) and even higher concentrations aloft (∼150 ppbv of ozone found 2 km above the surface) as compared to more typical profiles. Integrated ozone columns from the surface to 5 km increased from 17–22 DU (measured in the absence of the polluted air mass) to 34–36 DU on 19 and 20 July. The average on 20 July 2004 of the 8-hour maximum ozone values recorded by surface monitors across the Houston area was the highest of any July day during the 2001–2005 period. The combination of the ozone observations, satellite data, and model results implicates the biomass burning effluence originating in Alaska and Canada a week earlier in exacerbating pollution levels seen in Houston