Strong magnetic fluctuations can provide a coupling mechanism for electrons that leads to unconventional superconductivity. Magnetic order and superconductivity have been found to coexist in a number of magnetically mediated superconductors, but these order parameters generally compete. We report that close to the upper critical field, CeCoIn5 adopts a multicomponent ground state that simultaneously carries cooperating magnetic and superconducting orders. Suppressing superconductivity in a first-order transition at the upper critical field leads to the simultaneous collapse of the magnetic order, showing that superconductivity is necessary for the magnetic order. A symmetry analysis of the coupling between the magnetic order and the superconducting gap function suggests a form of superconductivity that is associated with a nonvanishing momentum.

We report pressure-induced superconductivity in a single crystal of CaFe 2 As 2 . At atmospheric pressure, this material is antiferromagnetic below 170 K but under an applied pressure of 0.69 GPa becomes superconducting, with a transition temperature T c exceeding 10 K. The rate of T c suppression with applied magnetic field is −0.7 K T −1 , giving an extrapolated zero-temperature upper critical field of 10-14 T.

Understanding the origin of superconductivity in strongly correlated electron systems continues to be at the forefront of the unsolved problems of physics 1 . Among the heavy f-electron systems, CeCoIn 5 is one of the most fascinating, as it shares many of the characteristics of correlated d-electron high-T c cuprate and pnictide superconductors 2-4 , including competition between antiferromagnetism and superconductivity 5 . Although there has been evidence for unconventional pairing in this compound 6-11 , high-resolution spectroscopic measurements of the superconducting state have been lacking. Previously, we have used high-resolution scanning tunnelling microscopy (STM) techniques to visualize the emergence of heavy fermion excitations in CeCoIn 5 and demonstrate the composite nature of these excitations well above T c (ref. 12). Here we extend these techniques to much lower temperatures to investigate how superconductivity develops within a strongly correlated band of composite excitations. We find the spectrum of heavy excitations to be strongly modified just before the onset of superconductivity by a suppression of the spectral weight near the Fermi energy (E F ), reminiscent of the pseudogap state 13,14 in the cuprates. By measuring the response of superconductivity to various perturbations, through both quasiparticle interference (QPI) and local pair-breaking experiments, we demonstrate the nodal d-wave character of superconducting pairing in CeCoIn 5 .CeCoIn 5 undergoes a superconducting transition at 2.3 K. Despite evidence of unconventional pairing, consensus on the mechanism of pairing and direct experimental verification of the order parameter symmetry are still lacking [6][7][8][9]11 . Moreover, experiments have suggested that superconductivity in this compound emerges from a state of unconventional quasiparticle excitations with a pseudogap phase similar to that found in underdoped high-T c cuprates [15][16][17] . Previously, we demonstrated that scanning tunnelling spectroscopic techniques can be used to directly visualize the emergence of heavy fermion excitations in CeCoIn 5 and their quantum critical nature 12 . Through these measurements, we also demonstrated the composite nature of heavy quasiparticles and showed their band formation as the f -electrons hybridize with the spd-electrons starting at 70 K, well above T c (ref. 12). This previous breakthrough, together with our recent development of high-resolution millikelvin STM, offers a unique opportunity to measure how superconductivity emerges in a heavy electron system. Figure 1 shows STM topographs of the two commonly observed atomically ordered surfaces of CeCoIn 5 produced after the cleaving of single crystals in situ in the ultra-high vacuum environment 1 Joseph Henry Laboratories and Department of Physics, Princeton University, Princeton, New Jersey 08544, USA, 2 Condensed Matter and Magnet Science, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA. † These authors contributed equally to this work. *e-mail: yazdani@pr...

No abstract