[1] High-resolution geochemical records from a depth transect through the Cenomanian/Turonian (C/T) Tarfaya Basin (northwest African Shelf) reveal high-amplitude fluctuations in accumulation rates of organic carbon (OC), redox-sensitive and sulphide-forming trace metals, and biomarkers indicative of photic zone euxinia. These fluctuations are in general coeval and thus imply a strong relationship of OC burial and water column redox conditions. The pacing and regularity of the records and the absence of a prominent continental signature suggest a dynamic depositional setting linked to orbital and higher-frequency forcing. Determining the dominant frequency depends on the definition of the most pronounced oceanic anoxic event (OAE2) and its duration. We propose that eccentricity is the main forcing factor at Tarfaya and controlled fluctuations in wind-driven upwelling of nutrient-rich, oxygen-depleted intermediate waters from the adjacent Atlantic and the periodic development of photic zone and bottom water euxinia on the midCretaceous northwest African shelf. Accumulation records clearly identify the basin center as the primary site of sediment deposition with highest temporal variability and an up to six-fold increase in OC burial from $2 g/m 2 Á yr prior to the OAE2 to $12 g/m 2 Á yr during the OAE2. Photic zone and bottom water euxinia alternated with periods of greater oxygenation of the water column in response to climate forcing. Mass balance calculations imply that $2% of the overall global excess OC burial associated with the OAE2 was deposited in the Tarfaya Basin, an area that represented only $0.05% of the total global C/T ocean floor. In fact, the lateral extent of similar black shales along the African continental margin indicates that this part of the ocean contributed significantly to the global increase in organic carbon burial during the OAE2.Citation: Kolonic, S., et al. (2005), Black shale deposition on the northwest African Shelf during the Cenomanian/Turonian oceanic anoxic event: Climate coupling and global organic carbon burial, Paleoceanography, 20, PA1006,

Cenozoic continental sedimentary deposits of the Southern Atlas named ªImerhane Groupº crop out (a) in the Ouarzazate foreland basin between the Precambrian basement of the Anti Atlas and the uplifted limestone dominated High Atlas, and (b) in the Aït Kandoula and Aït Seddrat nappes where Jurassic strata detached from the basement have been thrust southwards over the Ouarzazate Basin. New biostratigraphic and geochronological data constraining the final Eocene marine regression, the characterization of the new ªAït Ouglif Detrital Formationº presumed to be of Oligocene age, and the new stratigraphic division proposed for the Continental Imerhane Group clarify the major tectonogenetic alpidic movements of the Central High Atlas Range. Four continental formations are identified at regional scale. Their emplacement was governed principally by tectonic but also by eustatic controls. The Hadida and Aït Arbi formations (Upper Eocene) record the major Paleogene regression. They are composed of marginolittoral facies (coastal sabkhas and fluviatile systems) and reflect incipient erosion of the underlying strata and renewed fluvial drainage. The Aït Ouglif Formation (presumed Oligocene) had not been characterized before. It frequently overlies all earlier formations with an angular unconformity. It includes siliciclastic alluvial deposits and is composed predominantly of numerous thin fining-upward cycles. The Aït Kandoula Formation (Miocene±Pliocene) is discordant, extensive, and represents a thick coarsening-upward megasequence. It is composed of palustro-lacustrine deposits in a context of alluvial plain with localized sabkhas, giving way to alluvial fans and fluviatile environments. The Upper Conglomeratic Formation (Quaternary) is the trace of a vast conglomeratic pediment, forming an alluvial plain and terraces. The second and third formations correspond to two megasequences engendered by the uplift of the Central High Atlas in two major compressive phases during late Oligocene and Miocene±Pliocene times. These two geodynamic events were separated by a tectonically calm phase, materialized by palustro-lacustrine sedimentation ). Tectono-sedimentary analysis of the two megasequences shows that the basin structure and depositional processes were controlled by the compressive tectonic context generated by the collision of North Africa and Iberia in Tertiary times (Jacobshagen et al. 1988). The Quaternary Formation was apparently controlled by a tectonic continuum and by climatic variations.

We investigated the onset and development of Cretaceous Oceanic Anoxic Event 2 (OAE2) in a newly drilled core (SN°4) from the Tarfaya Basin (southern Morocco), where this interval is unusually expanded. High‐resolution (centimeter‐scale equivalent to centennial) analysis of bulk organic and carbonate stable isotopes and of carbonate and organic carbon content in combination with XRF scanner derived elemental distribution reveal that the ocean‐climate system behaved in a highly dynamic manner prior to and during the onset of OAE2. Correlation with the latest orbital solution indicates that the main carbon isotope shift occurred during an extended minimum in orbital eccentricity (~400 kyr cycle). Shorter‐term fluctuations in carbonate and organic carbon accumulation and in sea level related terrigenous discharge were predominantly driven by variations in orbital obliquity. Negative excursions in organic and carbonate δ13C preceded the global positive δ13C shift marking the onset of OAE2, suggesting injection of isotopically depleted carbon into the atmosphere. The main δ13C increase during the early phase of OAE2 in the late Cenomanian was punctuated by a transient plateau. Maximum organic carbon accumulation occurred during the later part of the main δ13C increase and was associated with climate cooling events, expressed as three consecutive maxima in bulk carbonate δ18O. The extinctions of the thermocline dwelling keeled planktonic foraminifers Rotalipora greenhornensis and Rotalipora cushmani occurred during the first and last of these cooling events and were likely associated with obliquity paced, ocean‐wide expansions, and intensifications of the oxygen minimum zone, affecting their habitat space on a global scale.

a b s t r a c tProfound biotic changes accompanied the late Cenomanian d 13 C excursion and OAE2 in planktic foraminifera in the Tarfaya Basin of Morocco. Planktic foraminifera experienced a severe turnover , though no mass extinction, beginning with the rapid d 13 C excursion and accelerating with the influx of oxic bottom waters during the first peak and trough of the excursion. Species extinctions equaled the number of evolving species, though only the disaster opportunists Guembelitria and Hedbergella thrived along with a low oxygen tolerant benthic assemblage. The succeeding d 13 C plateau and organic-rich black shale deposition marks the anoxic event and maximum biotic stress accompanied by a prolonged drop in diversity to just two species, the dominant (80-90%) low oxygen tolerant Heterohelix moremani and surface dweller Hedbergella planispira. After the anoxic event other species returned, but remained rare and sporadically present well into the lower Turonian, whereas Heterohelix moremani remained the single dominant species. The OAE2 biotic turnover suggests that the stress to calcareous plankton was related to changes in the watermass stratification, intensity of upwelling, nutrient flux and oxic levels in the water column driven by changes in climate and oceanic circulation. Results presented here demonstrate a 4-stage pattern of biotic response to the onset, duration, and recovery of OAE2 that is observed widely across the Tethys and its bordering epicontinental seas.

a b s t r a c tWith a multi-proxy approach, an attempt was made to constrain productivity and bottom-water redox conditions and their effects on the phosphorus accumulation rate at the Mohammed Plage section on the Tarfaya coast, Morocco, during the Cenomanian-Turonian Anoxic Event (OAE 2). A distinct d 13 C org isotope excursion of þ2.5& occurs close to the top of the section. The unusually abrupt shift of the isotope excursion and disappearance of several planktonic foraminiferal species (e.g. Rotalipora cushmani and Rotalipora greenhornensis) in this level suggests a hiatus of between 40-60 kyrs at the excursion onset. Nevertheless, it was possible to determine both the long-term environmental history as well as the processes that took place immediately prior to and during OAE 2. TOC% values increase gradually from the base of the section to the top (from w2.5% to w10%). This is interpreted as the consequence of a longterm eustatic sea-level rise and subsidence causing the encroachment of less oxic waters into the Tarfaya Basin. Similarly a reduction in the mineralogically constructed 'detrital index' can be explained by the decrease in the continental flux of terrigenous material due to a relative sea-level rise. A speciation of phosphorus in the upper part of the section, which spans the start and mid-stages of OAE 2, shows overall higher abundances of P reactive mass accumulation rates before the isotope excursion onset and lower values during the plateau. Due to the probable short hiatus, the onset of the decrease in phosphorus content relative to the isotope excursion is uncertain, although the excursion plateau already contains lower concentrations. The C org /P total and V/Al ratios suggest that this reduction was mostly likely caused by a decrease in the available bottom oxygen content (probably as a result of higher productivity) and a corresponding fall in the phosphorus retention ability of the sediment. Productivity appears to have remained high during the isotope plateau possibly due to a combination of ocean-surface fertilisation via increased aridity (increased K/Al and Ti/Al ratios) and/or higher dissolved inorganic phosphorus content in the water column as a result of the decrease in sediment P retention. The evidence for decreased P-burial has been observed in many other palaeoenvironments during OAE 2. Tarfaya's unique upwelling paleosituation provides strong evidence that the nutrient recycling was a global phenomenon and therefore a critical factor in starting and sustaining OAE 2.