A comparative study of pure, SiC, and C doped MgB2 wires has revealed that the SiC doping allowed C substitution and MgB2 formation to take place simultaneously at low temperatures. C substitution enhances H_{c2}, while the defects, small grain size, and nanoinclusions induced by C incorporation and low-temperature processing are responsible for the improvement in J_{c}. The irreversibility field (H_{irr}) for the SiC doped sample reached the benchmarking value of 10 T at 20 K, exceeding that of NbTi at 4.2 K. This dual reaction model also enables us to predict desirable dopants for enhancing the performance properties of MgB2.
Fe-clad MgB 2 long tapes have been fabricated using a powder-in-tube technique. An Mg + 2B mixture was used as the central conductor core and reacted in-situ to form MgB 2 . The tapes were sintered in pure Ar at 800 o C for 1 h at ambient pressure. SEM shows a highly dense core with a large grain size of 100 µm. The Fe clad tape shows a sharp transition with transition width of ∆T c of 0.2 K and T c0 at 37.5 K. We have achieved the highest transport critical current reported so far at 1.6 × 10 4 A/cm 2 for both 29.5 K in 1 Tesla and 33 K in null field. R-T and critical current were also measured for fields perpendicular and parallel to the tape plane. The iron cladding shielded on the core from the applied external field, with the shielding being less effective for the field in the tape plane. Fe cladding may be advantageous for some applications as it could reduce the effects of both the self-field and external fields.
A comprehensive study of selected properties of four (TiZrNbCu)1-xNix (x ≤ 0.25) amorphous high entropy alloys (a-HEA) has been performed. The samples were ribbons about 20 µm thick and their fully amorphous state was verified by X-ray diffraction and thermal analysis. The surface morphology, precise composition and the distribution of components were studied with a Scanning electron microscope (SEM) with an energy dispersive spectroscopy (EDS) attachment. The properties selected were the melting temperature (Tm), the low temperature specific heat (LTSH), the magnetic susceptibility χexp and the Young´s modulus (E). Whereas LTSH and χexp were measured for the as-cast samples, E was measured both for as-cast samples and relaxed samples (after a short anneal close to the glass transition temperature). The LTSH showed that the electronic density of states at the Fermi level, N0(EF), decreases with increasing x, whereas the Debye temperature (θD) increases with x. This is similar to what is observed in binary and ternary amorphous alloys of early transition metals (TE) with late transition metals (TL) and indicates that N0(EF) is dominated by the d-electrons of the TE.The LTSH also showed the absence of superconductivity down to 1.8K and indicated the emergence of the Boson peak above 4K in all alloys.The free-electron like paramagnetic contribution to χexp also decreases with x, whereas E, like θD, increases with x, indicating enhanced interatomic bonding on addition of Ni. The applicability of the rule of mixtures to these and other similar HEAs is briefly discussed.
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