Lead originating from coal burning, gasoline burning, and ore smelting was identified in 210Pb-dated profiles through eight peat bogs distributed over an area of 60,000 km2. The Sphagnum-dominated bogs were located mainly in mountainous regions of the Czech Republic bordering with Germany, Austria, and Poland. Basal peat 14C-dated at 11,000 years BP had a relatively high 206Pb/207Pb ratio (1.193). Peat deposited around 1800 AD had a lower 206Pb/207Pb ratio of 1.168-1.178, indicating that environmental lead in Central Europe had been largely affected by human activity (smelting) even before the beginning of the Industrial Revolution. Five of the sites exhibited a nearly constant 206Pb/207Pb ratio (1.175) throughout the 19th century, resembling the "anthropogenic baseline" described in Northern Europe (1.17). At all sites, the 206Pb/207Pb ratio of peat decreased at least until 1980; at four sites, a reversal to more radiogenic values (higher 206Pb/207Pb), typical of easing pollution, was observed in the following decade (1980-1990). A time series of annual outputs for 14 different mining districts dispersing lead into the environment has been constructed for the past 200 years. The production of Ag-Pb, coal, and leaded gasoline peaked in 1900, 1980, and 1980, respectively. In contrast to other European countries, no peak in annual Pb accumulation rates was found in 1900, the year of maximum ore smelting. The highest annual Pb accumulation rates in peat were consistent with the highest Pb emission rates from coal-fired power plants and traffic (1980). Although maximum coal and gasoline production coincided in time, their isotope ratios were unique. The mean measured 206Pb/207Pb ratios of local coal, ores, and gasoline were 1.19, 1.16, and 1.11, respectively. A considerable proportion of coal emissions, relative to gasoline emisions, was responsible for the higher 206Pb/207Pb ratios in the recent atmosphere (1.15) compared to Western Europe (1.10). As in West European countries, the gasoline sold in the Czech Republic during the Communist era (1948-1989) contained an admixture of low-radiogenic Precambrian lead from Australia.
Aim: The regional co-occurrence of contrasting bioclimatic elements (warm-temperate, continental, boreal, arctic-alpine) may be shaped by the distribution of their glacial or post-glacial refugia. We tested this hypothesis using pollen proxies in a region where such refugia are expected, but not unequivocally demonstrated.Location: East-Central Europe (Western Carpathians and adjacent regions). Methods:We compiled pollen spectra from 112 sites distributed across various landscapes for six time-periods from the Late Glacial to the present. Compositional patterns were assessed by principal coordinates analyses (PCoA) with a sensitivity analysis based on a bootstrap technique. Site PCoA scores were interpolated geographically and correlated with palaeoclimatic models.Results: Consistently over the last 15,000 years, the first ordination axis sorted samples according to the proportion of deciduous temperate trees, while the second axis consistently followed an altitudinal gradient that coincided with temperature.The principal gradient was more important than the altitudinal gradient except for the Late Glacial and Bronze & Iron Ages, when both gradients were of similar importance. The fine-grained pattern in the present mountain landscape was formed as late as during early modern colonization.Main conclusions: Since the Late Glacial, the landscape has been differentiated into temperate, continental and cold regions. This finding supports the hypothesis that refugia are a key factor for understanding current biogeography in Central Europe.The Late Glacial occurrence of temperate trees is unlikely to be explained only by gradual migrations from southern Europe. Humid but relatively warm mountains hence might have acted as glacial refugia of temperate forest species, while lowlands and leeward basins might have acted as post-glacial refugia of steppe grasslands. The strong contrast between forested (temperate) and more open continental landscapes during the Early Holocene seems to correspond with recent diversity patterns. Our results highlight the relevance of integrating past landscape trajectories into modern biogeographical models.
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