We report on chemically prepared silver nanowires (diameters around 100 nm) sustaining surface plasmon modes with wavelengths shortened to about half the value of the exciting light. As we find by scattered light spectroscopy and near-field optical microscopy, the nonradiating character of these modes together with minimized damping due to the well developed wire crystal structure gives rise to large values of surface plasmon propagation length and nanowire end face reflectivity of about 10 microm and 25%, respectively. We demonstrate that these properties allow us to apply the nanowires as efficient surface plasmon Fabry-Perot resonators.
We map the complete plasmonic spectrum of silver nanodisks
by electron
energy loss spectroscopy and show that the mode which couples strongest
to the electron beam has radial symmetry with no net dipole moment.
Therefore, this mode does not couple to light and has escaped from
observation in optical experiments. This radial breathing mode has
the character of an extended two-dimensional surface plasmon with
a wavenumber determined by the circular disk confinement. Its strong
near fields can impact the hybridization in coupled plasmonic nanoparticles
as well as couplings with nearby quantum emitters.
Polymer/copper indium sulfide (CIS) nanocomposite solar cells are prepared via a capper free in situ preparation route using copper and indium xanthates as precursors, which decompose and form CIS nanoparticles in the polymer matrix during a mild thermal treatment. The solar cells generate current in a wide range of the solar spectrum and exhibit efficiencies up to 2.8%.
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