A carbon-rich black layer, dating to Ϸ12.9 ka, has been previously identified at Ϸ50 Clovis-age sites across North America and appears contemporaneous with the abrupt onset of Younger Dryas (YD) cooling. The in situ bones of extinct Pleistocene megafauna, along with Clovis tool assemblages, occur below this black layer but not within or above it. Causes for the extinctions, YD cooling, and termination of Clovis culture have long been controversial. In this paper, we provide evidence for an extraterrestrial (ET) impact event at Х12.9 ka, which we hypothesize caused abrupt environmental changes that contributed to YD cooling, major ecological reorganization, broad-scale extinctions, and rapid human behavioral shifts at the end of the Clovis Period. Clovis-age sites in North American are overlain by a thin, discrete layer with varying peak abundances of (i) magnetic grains with iridium, (ii) magnetic microspherules, (iii) charcoal, (iv) soot, (v) carbon spherules, (vi) glass-like carbon containing nanodiamonds, and (vii) fullerenes with ET helium, all of which are evidence for an ET impact and associated biomass burning at Ϸ12.9 ka. This layer also extends throughout at least 15 Carolina Bays, which are unique, elliptical depressions, oriented to the northwest across the Atlantic Coastal Plain. We propose that one or more large, low-density ET objects exploded over northern North America, partially destabilizing the Laurentide Ice Sheet and triggering YD cooling. The shock wave, thermal pulse, and event-related environmental effects (e.g., extensive biomass burning and food limitations) contributed to end-Pleistocene megafaunal extinctions and adaptive shifts among PaleoAmericans in North America.comet ͉ iridium ͉ micrometeorites ͉ nanodiamonds ͉ spherules

Airbursts/impacts by a fragmented comet or asteroid have been proposed at the Younger Dryas onset (12.80 ± 0.15 ka) based on identification of an assemblage of impact-related proxies, including microspherules, nanodiamonds, and iridium. Distributed across four continents at the Younger Dryas boundary (YDB), spherule peaks have been independently confirmed in eight studies, but unconfirmed in two others, resulting in continued dispute about their occurrence, distribution, and origin. To further address this dispute and better identify YDB spherules, we present results from one of the largest spherule investigations ever undertaken regarding spherule geochemistry, morphologies, origins, and processes of formation. We investigated 18 sites across North America, Europe, and the Middle East, performing nearly 700 analyses on spherules using energy dispersive X-ray spectroscopy for geochemical analyses and scanning electron microscopy for surface microstructural characterization. Twelve locations rank among the world's premier end-Pleistocene archaeological sites, where the YDB marks a hiatus in human occupation or major changes in site use. Our results are consistent with melting of sediments to temperatures >2,200°C by the thermal radiation and air shocks produced by passage of an extraterrestrial object through the atmosphere; they are inconsistent with volcanic, cosmic, anthropogenic, lightning, or authigenic sources. We also produced spherules from wood in the laboratory at >1,730°C, indicating that impactrelated incineration of biomass may have contributed to spherule production. At 12.8 ka, an estimated 10 million tonnes of spherules were distributed across ∼50 million square kilometers, similar to well-known impact strewnfields and consistent with a major cosmic impact event.Clovis-Folsom | lechatelierite | tektite | wildfires

It has been proposed that fragments of an asteroid or comet impacted Earth, deposited silica-and iron-rich microspherules and other proxies across several continents, and triggered the Younger Dryas cooling episode 12,900 years ago. Although many independent groups have confirmed the impact evidence, the hypothesis remains controversial because some groups have failed to do so. We examined sediment sequences from 18 dated Younger Dryas boundary (YDB) sites across three continents (North America, Europe, and Asia), spanning 12,000 km around nearly one-third of the planet. All sites display abundant microspherules in the YDB with none or few above and below. In addition, three sites (Abu Hureyra, Syria; Melrose, Pennsylvania; and Blackville, South Carolina) display vesicular, high-temperature, siliceous scoria-like objects, or SLOs, that match the spherules geochemically. We compared YDB objects with melt products from a known cosmic impact (Meteor Crater, Arizona) and from the 1945 Trinity nuclear airburst in Socorro, New Mexico, and found that all of these high-energy events produced material that is geochemically and morphologically comparable, including: (i) high-temperature, rapidly quenched microspherules and SLOs; (ii) corundum, mullite, and suessite (Fe 3 Si), a rare meteoritic mineral that forms under high temperatures; (iii) melted SiO 2 glass, or lechatelierite, with flow textures (or schlieren) that form at >2,200°C; and (iv) particles with features indicative of high-energy interparticle collisions. These results are inconsistent with anthropogenic, volcanic, authigenic, and cosmic materials, yet consistent with cosmic ejecta, supporting the hypothesis of extraterrestrial airbursts/impacts 12,900 years ago. The wide geographic distribution of SLOs is consistent with multiple impactors.tektite | microcraters | oxygen fugacity | trinitite Manuscript TextThe discovery of anomalous materials in a thin sedimentary layer up to a few cm thick and broadly distributed across several continents led Firestone et al. (1) to propose that a cosmic impact (note that "impact" denotes a collision by a cosmic object either with Earth's surface, producing a crater, or with its atmosphere, producing an airburst) occurred at 12.9 kiloannum (ka; all dates are in calendar or calibrated ka, unless otherwise indicated) near the onset of the Younger Dryas (YD) cooling episode. This stratum, called the YD boundary layer, or YDB, often occurs directly beneath an organic-rich layer, referred to as a black mat (2), that is distributed widely over North America and parts of South America, Europe, and Syria. Black mats also occur less frequently in quaternary deposits that are younger and older than 12.9 ka (2). The YDB layer contains elevated abundances of iron-and silica-rich microspherules (collectively called "spherules") that are interpreted to have originated by cosmic impact because of their unique properties, as discussed below. Other markers include sediment and magnetic grains with elevated iridium concentrations and exot...

A B S T R A C TPart 1 of this study investigated evidence of biomass burning in global ice records, and here we continue to test the hypothesis that an impact event at the Younger Dryas boundary (YDB) caused an anomalously intense episode of biomass burning at ∼12.8 ka on a multicontinental scale (North and South America, Europe, and Asia). Quantitative analyses of charcoal and soot records from 152 lakes, marine cores, and terrestrial sequences reveal a major peak in biomass burning at the Younger Dryas (YD) onset that appears to be the highest during the latest Quaternary. For the Cretaceous-Tertiary boundary (K-Pg) impact event, concentrations of soot were previously utilized to estimate the global amount of biomass burned, and similar measurements suggest that wildfires at the YD onset rapidly consumed ∼10 million km 2 of Earth's surface, or ∼9% of Earth's biomass, considerably more than for the K-Pg impact. Bayesian analyses and age regressions demonstrate that ages for YDB peaks in charcoal and soot across four continents are synchronous with the ages of an abundance peak in platinum in the Greenland Ice Sheet Project 2 (GISP2) ice core and of the YDB impact event (12,835-12,735 cal BP). Thus, existing evidence indicates that the YDB impact event caused an anomalously large episode of biomass burning, resulting in extensive atmospheric soot/dust loading that triggered an "impact winter." This, in turn, triggered abrupt YD cooling and other climate changes, reinforced by climatic feedback mechanisms, including Arctic sea ice expansion, rerouting of North American continental runoff, and subsequent ocean circulation changes.

The Younger Dryas boundary (YDB) cosmic-impact hypothesis is based on considerable evidence that Earth collided with fragments of a disintegrating ≥100-km-diameter comet, the remnants of which persist within the inner solar system ∼12,800 y later. Evidence suggests that the YDB cosmic impact triggered an "impact winter" and the subsequent Younger Dryas (YD) climate episode, biomass burning, late Pleistocene megafaunal extinctions, and human cultural shifts and population declines. The cosmic impact deposited anomalously high concentrations of platinum over much of the Northern Hemisphere, as recorded at 26 YDB sites at the YD onset, including the Greenland Ice Sheet Project 2 ice core, in which platinum deposition spans ∼21 y (∼12,836-12,815 cal BP). The YD onset also exhibits increased dust concentrations, synchronous with the onset of a remarkably high peak in ammonium, a biomass-burning aerosol. In four ice-core sequences from Greenland, Antarctica, and Russia, similar anomalous peaks in other combustion aerosols occur, including nitrate, oxalate, acetate, and formate, reflecting one of the largest biomass-burning episodes in more than 120,000 y. In support of widespread wildfires, the perturbations in CO 2 records from Taylor Glacier, Antarctica, suggest that biomass burning at the YD onset may have consumed ∼10 million km 2 , or ∼9% of Earth's terrestrial biomass. The ice record is consistent with YDB impact theory that extensive impact-related biomass burning triggered the abrupt onset of an impact winter, which led, through climatic feedbacks, to the anomalous YD climate episode.