The influence of the plankton community structure on carbon dynamics was studied in the surface waters of the Argentinean continental shelf (SW Atlantic Ocean) in summer and fall 2002, 2003 and 2004. The horizontal changes in plankton community respiration (R), net community production (NCP) and gross primary production (GPP) were (1) compared with the difference in the partial pressure of CO 2 (pCO 2 ) between the sea surface and the atmosphere (ΔpCO 2 ), (2) compared with oxygen saturation and (3) related to the microscopic phytoplankton assemblages. This area, which has recently been shown to be a CO 2 sink, had an average surface oxygen saturation of 108.1%, indicating that net photosynthesis could have played a dominant role in the CO 2 dynamics. At most stations, the production:respiration (GPP:R) ratio was greater than 1, indicating that planktonic communities were autotrophic; the average GPP:R ratio for the whole study was 2.99. Phytoplankton biomass (chlorophyll a) and NCP showed an inverse relationship with ΔpCO 2 and a direct relationship with %O 2 saturation when phytoplankton assemblages were dominated by diatoms (30% of the stations). This was not the case when small (≤5 µm) flagellates were the most abundant organisms. Although NCP was mostly positive for both groups of stations (i.e. diatom-dominated or small flagellate-dominated), other physical and biological processes are thought to modify the CO 2 dynamics when small flagellates are the prevailing phytoplankton group.

[1] Measuring ultraviolet radiation in the Antarctic region, where weather conditions are extremely challenging, is a demanding task. Proper quality control of the measurements and quality assurance of the data, which are the basis of all scientific use of data, has to be especially well planned and executed. In this paper we show the importance of proper quality assurance and describe the methods used to successfully operate the NILU-UV multichannel radiometers of the Antarctic network stations at Ushuaia, 54°S, and Marambio, 64°S. According to our experience, even though multichannel instruments are supposed to be rather stable as a function of time, severe drifts can occur in the sensitivity of the channels under these harsh conditions. During 2000-2003 the biggest drifts were 35%, both at Ushuaia and Marambio, with the sensitivity of the channels dropping at different rates. Without proper corrections in the data, this would have seriously affected the calculated UV dose rates. As part of the quality assurance of the network a traveling reference NILU-UV, which was found to be stable, was used to transfer the desired irradiance scale to the site NILU-UV data. Relative lamp tests were used to monitor the stability of the instruments. Each site NILU-UV was scaled channel by channel to the traveling reference by performing solar comparisons. The method of scaling each channel separately was found to be successful, even though the differences between the raw data of the site NILU-UV and the reference instruments were, before the data correction, as much as 40%. After the correction, the mean ratios of erythemally weighted UV dose rates measured during the solar comparisons in 2000-2003 between the reference NILU-UV and the site NILU-UV were 1.007 ± 0.011 and 1.012 ± 0.012 for Ushuaia and Marambio, respectively, when the solar zenith angle varied up to 80°. These results make possible the scientific use of NILU-UV data measured simultaneously at quite different locations, e.g., the Antarctic and Arctic, and the method presented is also practicable for other multichannel radiometer networks.

Abstract. Radiosonde temperature profiles from Belgrano (78 • S) and other Antarctic stations have been compared with European Centre for Medium-Range Weather Forecasting (ECMWF) and National Centers for Environmental Prediction (NCEP) operational analyses during the winter of 2003. Results show good agreement between radiosondes and NCEP and a bias in the ECMWF model which is height and temperature dependent, being up to 3 • C too cold at 80 and 25-30 hPa, and hence resulting in an overestimation of the predicted potential PSC areas. Here we show the results of the comparison and discuss the potential implications that this bias might have on the ozone depletion computed by Chemical Transport Models based on ECMWF temperature fields, after rejecting the possibility of a bias in the sondes at extreme low temperatures.

Polar stratospheric clouds (PSCs) play an important role in polar ozone depletion, since they are involved in diverse ozone destruction processes (chlorine activation, denitrification). The degree of that ozone reduction is depending on the type of PSCs, and hence on their occurrence. Therefore PSC characterization, mainly focused on PSC-type discrimination, is widely demanded. The backscattering (R) and volume linear depolarization (δ^V) ratios are the parameters usually used in lidar measurements for PSC detection and identification. In this work, an improved version of the standard NASA/Micro Pulse Lidar (MPL-4), which includes a built-in depolarization detection module, has been used for PSC observations above the coastal Antarctic Belgrano II station (Argentina, 77.9° S 34.6° W, 256 m a.s.l.) since 2009. Examination of the MPL-4 δ^V feature as a suitable index for PSC-type discrimination is based on the analysis of the two-channel data, i.e., the parallel (p-) and perpendicular (s-) polarized MPL signals. This study focuses on the comparison of coincident δ^V-profiles as obtained from ground-based MPL-4 measurements during three Antarctic winters with those reported from the space-borne lidar CALIOP (Cloud-Aerosol Lidar with Orthogonal Polarization) aboard the CALIPSO (Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation) satellite in the same period (83 simultaneous cases are analysed for 2009–2011 austral winter times). Three different approaches are considered for the comparison analysis between both lidar profile data sets in order to test the degree of agreement: the correlation coefficient (CC), as a measure of the relationship between both PSC vertical structures; the mean differences together with their root mean square (RMS) values found between data sets; and the percentage differences (BIAS), parameter also used in profiling comparisons between CALIOP and other ground-based lidar systems. All of them are examined as a function of the CALIPSO ground-track distance from the Belgrano II station. Results represent a relatively good agreement between both ground-based MPL-4 and space-borne CALIOP profiles of the volume linear depolarization ratio δ^V for PSC events, once the MPL-4 depolarization calibration parameters are applied. Discrepancies between CALIOP and MPL-4 profiles in vertical layering structure are enhanced from 20 km up, likely due to a decrease of the signal-to-noise ratio (SNR) for both lidar systems at those altitudes. Regarding the results obtained from the mean and the percentage differences found between MPL-4 and CALIOP δ^V profiles, a predominance of negative values is also observed, indicating a generalized underestimation of the MPL-4 depolarization as compared to that reported by CALIOP. However, absolute differences between those δ^V-profile data sets are no higher than a 10 ± 11% in average. Moreover, the degree of agreement between both lidar δ

Abstract. Over 20 years of stratospheric NO 2 vertical column density (VCD) data from ground-based zenith DOAS spectrometers were used for trend analysis, specifically, via multiple linear regression. Spectrometers from the Network for the Detection of Atmospheric Composition Change (NDACC) cover the subtropical latitudes in the Northern Hemisphere (Izaña, 28 • N), the southern Subantarctic (Ushuaia, 55 • S) and Antarctica (Marambio, 64 • S, and Belgrano, 78 • S). The results show that for the period 1993-2014, a mean positive decadal trend of +8.7 % was found in the subtropical Northern Hemisphere stations, and negative decadal trends of −8.7 and −13.8 % were found in the Southern Hemisphere at Ushuaia and Marambio, respectively; all trends are statistically significant at 95 %. Belgrano only shows a significant decadal trend of −11.3 % in the summer/autumn period. Most of the trends result from variations after 2005. The trend in the diurnal build-up per hour (DBU) was used to estimate the change in the rate of N 2 O 5 conversion to NO 2 during the day. With minor differences, the results reproduce those obtained for NO 2 . The trends computed for individual months show large monthto-month variability. At Izaña, the maximum occurs in December (+13.1 %), dropping abruptly to lower values in the first part of the year. In the Southern Hemisphere, the polar vortex dominates the monthly distributions of the trends. At Marambio, the maximum occurs in mid-winter (−21 %), whereas at the same time, the Ushuaia trend is close to its annual minimum (−7 %). The large difference in the trends at these two relatively close stations suggests a vortex shift towards the Atlantic/South American area over the past few years. Finally, the hemispheric asymmetry obtained in this work is discussed in the framework of the results obtained by previous works that considered tracer analysis and BrewerDobson circulation. The results obtained here provide evidence that the NO 2 produced by N 2 O decomposition is not the only cause of the observed trend in the stratosphere and support recent publications pointing to a dynamical redistribution starting in the past decade.