Near-infrared active photocatalytic properties of Bi2 WO6 nanosheets owing to the oxygen vacancies of the Bi2 WO6 nanosheets are reported. The broad spectrum photocatalyst, Bi2 WO6 -TiO2 nanobelt heterostructures, are obtained by assembling Bi2 WO6 nanocrystals on TiO2 nanobelts. The active light band of the novel hybrid photocatalyst with high photocatalytic activity covers full-spectrum solar light including the UV, visible, and near-infrared ranges.
This article presents combined stratigraphic, sedimentological, subsidence and provenance data for the Cretaceous–Palaeogene succession from the Zhepure Mountain of southern Tibet. This region records the northernmost sedimentation of the Tethyan passive margin of India, and this time interval represents the transition into continental collision with Asia. The uppermost Cretaceous Zhepure Shanpo and Jidula formations record the transition from pelagic into upper slope to delta‐plain environments. The Palaeocene–lower Eocene Zongpu Formation records a carbonate ramp that is overlain by the deep‐water Enba Formation (lower Eocene). The upper part of the Enba Formation records shallowing into a storm‐influenced, outer shelf environment. Detrital zircon U–Pb and Hf isotopic data indicate that the terrigenous strata of the Enba Formation were sourced from the Lhasa terrane. Unconformably overlying the Enba Formation is the Zhaguo Formation comprising fluvial deposits with evidence of recycling from the underlying successions. Backstripped subsidence analysis indicates shallowing during latest Cretaceous‐earliest Palaeocene time (Zhepure Shanpo and Jidula formations) driven by basement uplift, followed by stability (Zongpu Formation) until early Eocene time (Enba Formation) when accelerated subsidence occurred. The provenance, subsidence and stratigraphy suggest that the Enba and Zhaguo formations record foredeep and wedge‐top sedimentation respectively within the early Himalayan foreland basin. The underlying Zongpu Formation is interpreted to record the accumulation of a carbonate ramp at the margin of a submarine forebulge. The precursor tectonic uplift during latest Cretaceous time could either record surface uplift over a mantle plume related to the Réunion hotspot, or an early signal of lithospheric flexure related to oceanic subduction, continental collision or ophiolite obduction. The results indicate that the collision of India with Asia occurred before late Danian (ca. 62 Ma) time.
Combining 2D MoS2 with other transition metal sulfide is a promising strategy to elevate its electrochemical performances. Herein, heterostructures constructed using MnS nanoparticles embedded in MoS2 nanosheets (denoted as MnS‐MoS2) are designed and synthesized as anode materials for lithium/sodium‐ion batteries via a facile one‐step hydrothermal method. Phase transition and built‐in electric field brought by the heterostructure enhance the Li/Na ion intercalation kinetics, elevate the charge transport, and accommodate the volume expansion. The sequential phase transitions from 2H to 3R of MoS2 and α to γ of MnS are revealed for the first time. As a result, the MnS‐MoS2 electrode delivers outstanding specific capacity (1246.2 mAh g−1 at 1 A g−1), excellent rate, and stable long‐term cycling stability (397.2 mAh g−1 maintained after 3000 cycles at 20 A g−1) in Li‐ion half‐cells. Superior cycling and rate performance are also presented in sodium half‐cells and Li/Na full cells, demonstrating a promising practical application of the MnS‐MoS2 electrode. This work is anticipated to afford an in‐depth comprehension of the heterostructure contribution in energy storage and illuminate a new perspective to construct binary transition metal sulfide anodes.
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