The fabrics with copper or copper oxide deposition are of considerable interest because of exceptional antibacterial properties, which are useable in medical, textiles, and hygiene applications. Unfortunately, the conventional techniques take long processing time, complex equipment, and combination of several processing steps (nanoparticles synthesis and their deposition on fabrics). In this novel study, cathodic cage plasma deposition assisted with copper cathodic cage is used for the synthesis of the copper oxide on polyester and polyamide fabrics. For the enhancement of synthesis efficiency, the effect of cathodic cage lid thickness is also investigated. The samples are assessed by using scanning electron microscopy, elemental dispersive spectroscopy, and X-ray photoelectron spectroscopy. It is found that using cathodic cage plasma deposition, fabrics can be successfully synthesized by the copper oxide with comparatively small treatment time, cost-effectively, and environmentally friendly.Interestingly, cathodic cage plasma treatment is already proved to be working effectively on industrial scale; thus, it is predicted to be of noteworthy importance for fabrics processing on large-scale garments manufacturing and hospitals.
In this work, the influence of working pressure on the characteristics of the layers produced by the nitriding treatment on the AISI 316 austenitic stainless steel surface using the Cathodic Cage Plasma Nitriding technique (CCPN) is assessed. The treatments were carried out at a temperature of 723 K for 5 hours under working pressures of 120, 250 and 500 Pa. The morphology, microstructure and corrosion resistance were studied through optical microscopy, x-ray diffraction, and electrochemical potential curves. We analyzed the effects of working pressure on the layer thickness, microhardness and corrosion resistance. The E×i curves and the electrochemical impedance of polarized samples were measured in order to investigate the effect of the ion transfer inside the produced film placed into the anodic solution. The electrochemical impedance of the films were measured, and showed an apparent capacitive behavior. For treatment under a pressure of 120 Pa we found the nitrides Fe 3 N, Fe 4 N and CrN. For treatment at a pressure of 250 Pa, the CrN disappears and the observed phases are the nitrides Fe 3 N, Fe 4 N and the S-phase. For a treatment pressure of 500 Pa there is an increase in the corrosion resistance of nitrided layers, confirmed by the predominance of S-Phase in the x-ray diffraction pattern. On the other hand, the sample nitrided under the pressure of 250 Pa showed very unstable impedance behavior when immersed in NaCl solution, indicating that the treatment at this specific working pressure has a negative effect on the corrosion resistance of plasma nitrided AISI 316 stainless steel surfaces.
The cathodic cage plasma nitriding technique is used for thin film deposition. As such, the hollow cathode effect on cage holes is directly related to deposition efficiency. The objective of this work is to study the influence of the cathode length-to-diameter ratio in the deposition of fine copper films on samples placed internally and externally to the cathodic cage, in an argon atmosphere, for 3 h at 420 °C. Compositional, transmittance and morphological characterization of films show copper deposition in all treatments. However, it was observed that substrate temperatures during film deposition influence its morphology. As such, the formation of continuous film on internal samples is observed, whereas external samples show uniformally dispersed nanoparticles as well as the absence of dense film on substrates. As far as the length-to-diameter ratio is concerned, the 1.5 ratio presented the highest deposition efficiency.
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