The pine stems were cut from three different polluted environments – Ist trees degradation degree (weak pollution), IInd trees degradation degree (strong pollution) and IIIrd trees degradation degree (connected with very strong pollution). On the basis of obtained results it was stated that environmental pollution caused changes in late wood participation, as well as distribution of cellulose on the stem cross- and longitudinal section. It also changed cellulose content in bark from the butt-end section, which was about 26% regardless the degradation degree. The environmental pollution caused also an increase of viscometric average polymerization degree of cellulose in heartwood in relation to heartwood adjacent sapwood and sapwood from butt-end section. Regardless the degradation degree, cellulose polymerization degree in heartwood adjacent sapwood from the middle part of the stem was higher in comparison to sapwood and heartwood. Moreover, the environmental pollution caused the increase of viscometric average polymerization degree of cellulose in bark. The polymerization degree of cellulose in bark from the butt-end section of IIIrd degradation degree stems was 22% and 23% higher in comparison to the Ist and IInd degradation degree.
Black poplar (Populus nigra L.) was thermally modified in nitrogen atmosphere. The effects of the modification process on poplar wood were evaluated for temperatures: 160 °C, 190 °C, and 220 °C applied for 2 h; and 160 °C and 190 °C for 6 h. The percentual impact of temperature and time of modification on the properties of modified wood was analysed. The study permitted the identification correlations between the chemical composition and selected physical properties of thermally modified poplar wood. The dimensional stability of poplar wood was improved after thermal modification in nitrogen. The higher the temperature of modification, the lower the equilibrium moisture content (EMC) of black poplar. At the temperature of 220 °C, EMC was two times lower than the EMC of non-modified black poplar. It is also possible to reduce the dimensional changes of wood two-fold (at the modification temperature of 220 °C), both in radial and tangential directions, independently of the acclimatization conditions (from 34% to 98% relative humidity, RH). Similar correlations have been found for wood that has been soaked in water. Higher modification temperatures and longer processing times contributed to a lower swelling anisotropy (SA).
The chemical composition of poplar wood in relation to the species and age of trees. The contents of the following substances: mineral substances, extractives, cellulose, lignin, holocellulose, in wood from fastgrowing poplar species (Populus deltoides x maximowiczii and Populus trichocarpa Torr and A.Gray) aged 2.5, 3, 5 and 7 years were compared to the contents of the abovementioned substances in Populus nigra L. and Populus alba L. wood, aged about 30. According to other publications, the cellulose and lignin contents increase in parallel with the tree's age. On the other hand, the comparison of cellulose content in poplar wood showed that its content did not depend from the species of tree, age and growth environment. Whereas, the content of extractives in poplar wood was dependent from the species of tree, age and growth environment. The lignin content increased slightly as a tree age, but its content in 7-year-old wood was already similar to the level to be found in the wood at the age of about 30 years. About 30-year-old wood of P. nigra and P. alba contained less holocellulose as compared to its contents in P. deltoides x maximowiczii and P. trichocarpa wood, regardless of its age.
In this paper, the influence of physicochemical pretreatment methods on the chemical composition, enzymatic hydrolysis efficiency and porosity of fast-growing Populus trichocarpa wood was compared. Among the pretreatment methods, the liquid hot water (LHW) and steam explosion (SE) were used, which were performed at three different temperatures (160 °C, 175 °C and 190 °C) and two residence times (15 min and 1 h). The chemical composition, enzymatic hydrolysis and porosity analysis were done for native wood and solid fraction obtained after LHW and SE pretreatments. The porosity analysis was performed by inverse size exclusion chromatography method. Additionally, inhibitors of hydrolysis and fermentation processes in the liquid and solid fractions obtained after pretreatments were examined. Based on the results, it was found that the tested pretreatments caused the greatest changes in the chemical content of hemicelluloses. It was found that after LHW and SE pretreatments up to 99.1% or 94.0%, respectively, of hemicelluloses were removed from the obtained solid fraction. Moreover, the LHW and SE processes greatly enhanced the enzymatic digestibility of fast-growing poplar wood. The highest glucose yield was achieved after 15 min of SE pretreatment at 190 °C and was 676.4 mg/g pretreated biomass, while in the case of xylose the highest value (119.3 mg/g pretreated biomass) was obtained after 15 min of LHW pretreatment at 160 °C. Generally, after SE pretreatment process, more inhibitors were formed, and a greater effect of porous structure development was noticed than after LHW pretreatment. Despite this difference, the average glucose contents and yields after enzymatic hydrolysis of pretreated biomass were generally similar regardless of the pretreatment used.
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