[1] Based on acquired geophysical, geological and geotechnical data and modeling, we suggest hydrate dissolution to cause sediment collapse and pockmark formation in the Niger delta. Very high-resolution bathymetry data acquired from the Niger delta reveal the morphology of pockmarks with different shapes and sizes going from a small ring depression surrounding an irregular floor to more typical pockmarks with uniform depression. Geophysical data, in situ piezocone measurements, piezometer measurements and sediment cores demonstrate the presence of a common internal architecture of the studied pockmarks: inner sediments rich in gas hydrates surrounded by overpressured sediments. The temperature, pressure and salinity conditions of the studied area have allowed us to exclude the process of gas-hydrate dissociation (gas hydrate turns into free gas/water mixture) as a trigger of the observed pockmarks. Based on numerical modeling, we demonstrate that gas-hydrate dissolution (gas hydrate becomes mixture of water and dissolved gas) under a local decrease of the gas concentration at the base of the gas-hydrate occurrence zone (GHOZ) can explain the excess pore pressure and fluid flow surrounding the central hydrated area and the sediment collapse at the border of the GHOZ. The different deformation (or development) stages of the detected pockmarks confirm that a local process such as the amount of gas flow through faults rather than a regional one is at the origin of those depressions. Citation: Sultan, N., et al. (2010), Hydrate dissolution as a potential mechanism for pockmark formation in the Niger delta,

In previous works, it has been suggested that dissolution of gas hydrate can be responsible for pockmark formation and evolution in deep water Nigeria. It was shown that those pockmarks which are at different stages of maturation are characterized by a common internal architecture associated to gas hydrate dynamics. New results obtained by drilling into gas hydrate-bearing sediments with the MeBo seafloor drill rig in concert with geotechnical in situ measurements and pore water analyses indicate that pockmark formation and evolution in the study area are mainly controlled by rapid hydrate growth opposed to slow hydrate dissolution. On one hand, positive temperature anomalies, free gas trapped in shallow microfractures near the seafloor and coexistence of free gas and gas hydrate indicate rapid hydrate growth. On the other hand, slow hydrate dissolution is evident by low methane concentrations and almost constant sulfate values 2 m above the Gas Hydrate Occurrence Zone. Study Area and Main ObjectiveThe investigated area is located in deep water of Nigeria. Bathymetry in the area ranges from 1100 to 1250 m ( Figure 1). This area was previously shown to host a field of (sub) circular pockmarks [Georges and Cauquil, 2007]. These range in shape from a slightly depressed, hummocky seafloor to a much more pronounced depression and each of them is several tens to a few hundreds of meters wide (Figure 1). The various morphologies of the pockmarks suggest either distinct modes of formation or different evolutionary stages [Sultan et al., 2010]. Most of the pockmarks are located in an area bounded by two NW-SE trending deeprooted normal faults, which delineate a graben linked to the axis of anticline in the subsurface. Several deep and shallow faults and three N-S trending buried channels were recognized with high-resolution 3-D seismic data (Figure 1). The buried channels, which are situated between 80 ms and 180 ms (two-way travel time, TWTT) below the seabed, may have the potential of accumulating amounts of free gas and play therefore an important role for the gas hydrate distributions.Based on geophysical and sedimentological data, and in situ piezocone measurements, Sultan et al. [2007] have shown that pockmark-associated gas hydrate accumulated within a few meters thick sediment layers at shallow depth. In addition, Sultan et al. [2010] proposed that the formation of a circular depression around the gas hydrate occurrence zone (GHOZ) is related to multiple steps in the pockmark evolution. The sequence is starting with hydrate formation induced by upward migration of fluids oversaturated in gas through fracture systems followed by decrease of fluid flow resulting in gas undersaturation, hydrate dissolution, generation of excess pore pressure, and by concurrent collapse of the gas hydrate-bearing sediment structures. Respective analyses were mainly based on subseabed approaches, using piston cores and in situ piezocone geotechnical measurements with a maximum penetration of 30 m below seafloor (mbsf). Howe...

We present a new method to characterize free gas, gas hydrates and carbonate concretions occurrence which are considered as high-risk factors for sub-sea developments in the Niger delta. This method is based on the combination of 3D seismic data to the geotechnical site characterizations using piezocone CPTU tests (Cone Penetration Test with additional measurement of the pore water pressure). A special processing of the 3D seismic data has enabled the determination of the interval compressional velocity. Using the effective-medium theory, velocity anomalies (negative and positive) within the first 15 m were translated in gas hydrate and free gas distribution. The calibration of the P wave velocity anomalies was done thanks to in-situ geotechnical testing carried out during two oceanographic surveys (2003 and 2004). Comparison between in-situ testing, recovered cores and the prediction of the gas and the gas hydrate distribution based on the compressional wave velocity have shown that 3D seismic data is a valuable tool to identify heterogeneous areas but the use of the piezocone was essential to discriminate between gas hydrate occurrences and carbonate concretions' presence. Furthermore, in-situ compressional wave velocity (V p ) measurements have clearly demonstrated what it was suspected from the 3D seismic data, the co-existence in the study area between gas hydrate and free gas.

A joint research expedition between the French IFREMER and the German MARUM was conducted in 2011 using the R/V Pourquoi pas? to study gas hydrate distributions in a pockmark field (1141-1199 meters below sea surface) at the continental margin of Nigeria. The sea floor drill rig MeBo of MARUM was used to recover sediments as deep as 56.74 meters below seafloor. The presence of gas hydrates in specific core sections was deduced from temperature anomalies recorded during continuous records of infrared thermal scanning and anomalies in pore water chloride concentrations. In situ sediment temperature measurements showed elevated geothermal gradients of up to 258 °C/km in the center of the so-called pockmark A which is up to 4.6 times higher than that in the background sediment (72 °C/km). The gas hydrate distribution and thermal regime in the pockmark are largely controlled by the intensity, periodicity and direction of fluid flow. The joint interaction between fluid flow, gas hydrate formation and dissolution, and the thermal regime governs pockmark formation and evolution on the Nigerian continental margin.

[1] Gas hydrates were recovered by coring at the eastern border of a shale-cored anticline in the eastern Niger Delta. To characterize the link between faults and fluid release and to identify the role of fluid flow in the gas hydrate dynamics, three piezometers were deployed for periods ranging from 387 to 435 days. Two of them were deployed along a major fault linked to a shallow hydrocarbon reservoir while the third monitored the fluid pressure in a pockmark aligned above the same major fault. In addition, 10 ocean-bottom seismometers (OBS) were deployed for around 60 days. The piezometers simultaneously registered a prolonged fluid flow event lasting 90 days. During this time, OBS measurements record several episodic fluid release events. By combining and analyzing existing and newly acquired data, we show that the fluid-fault system operates according to the following three stages: (1) upward pore fluid migration through existing conduits and free gas circulation within several shallow sandy layers intersecting the major fault, (2) gas accumulation and pore pressure increases within sandy-silty layers, and (3) hydrofracturing and fluid pressure dissipation through sporadic degassing events, causing pore fluid circulation through shallow sandy layers and drawing overlying seawater into the sediment. This paper clearly demonstrates how an integrated approach based on seafloor observations, in situ measurements, and monitoring is essential for understanding fault-fluid-hydrate systems. Citation: Sultan, N., et al. (2011), Dynamics of fault-fluid-hydrate system around a shale-cored anticline in deepwater Nigeria,