Lightweight, robust, and thin aerogel films with multifunctionality are highly desirable to meet the technological demands of current society. However, fabrication and application of these multifunctional aerogel films are still significantly underdeveloped. Herein, we demonstrate a multifunctional aerogel film composed of strong aramid nanofibers (ANFs), conductive carbon nanotubes (CNTs), and hydrophobic fluorocarbon (FC) resin. The obtained hybrid aerogel film exhibits large specific surface area (232.8 m 2 •g −1 ), high electrical conductivity (230 S•m −1 ), and excellent hydrophobicity (contact angle of up to 137.0°) with exceptional Joule heating performance and supreme electromagnetic interference (EMI) shielding efficiency. The FC coating renders the hydrophilic ANF/CNT aerogel films hydrophobic, resulting in an excellent self-cleaning performance. The high electrical conductivity enables a low-voltage-driven Joule heating property and an EMI shielding effectiveness (SE) of 54.4 dB in the X-band at a thickness of 568 μm. The specific EMI SE is up to 33528.3 dB•cm 2 •g −1 , which is among the highest values of typical metal-, conducting-polymer-, or carbon-based composites. This multifunctional aerogel film holds great promise for smart garments, electromagnetic wave shielding, and personal thermal management systems.

With the advent of the 5G era, electronic systems have become more and more powerful, miniaturized, integrated ,and intelligent. The thermal management of electronic systems requires more efficiency and multiple functions for their practical applications, especially for the portable 5G electronic devices of the future, as the undesired heat can cause thermal discomfort or even thermal injury to people who use these electronic devices. Herein, two thermal management strategies based on boron nitride (BN) aerogel films have been proposed and demonstrated for portable devices. First, a flexible BN aerogel film with high porosity (>96%), large specific surface area (up to 982 m 2 g −1 ), and controllable thickness (in the range from 50 to 200 μm) was fabricated via molecular precursor assembly, sublimation drying, and pyrolysis reaction in sequence. The resulting BN aerogel film individuals, serving as a thermal insulation protecting layer in portable electronics, can significantly reduce heat transfer from electronics to skin. Second, BN phase change composite films, made by dipping BN aerogel films into the melts of the organic phase change materials (e.g., paraffin), can effectively cool the portable electronics as the organic phase change materials filled in the aerogel matrix can serve as a smart thermal-regulator to absorb the undesired heat via solid−liquid phase transition. These two typical strategies of the flexible BN aerogel film-directed thermal management could assist in efforts to miniaturize, integrate, and intelligentialize portable 5G electronic devices in the future.

By chemical cross-linking the amidoxime group onto dual-surfaces of natural ore materials,n amely halloysite nanotubes (HNTs), an efficient adsorbent, AO-HNTs,i s developed. AO-HNTs show high uranium adsorption capacity of 456.24 mg g À1 in 32 ppm uranium-spiked simulated seawater.I nn atural seawater,A O-HNTs reach the high uranium extraction capacity of 9.01 mg g À1 after 30 days field test. The dual-surface amidoximated hollown anotubular AO-HNTs exhibit more coordination active sites for uranium adsorption, which is attributed to the high and fast uranium adsorption capacity.Because of the stable natural ore structure,AO-HNTs also show long service life.B enefiting from the low cost of HNTs,the cost for uranium extraction from seawater is close to the uranium price in the spot uranium market, suggesting that AO-HNTs could be used for economical extraction of uranium from the oceans.

Epoxidized natural rubber-graphene (ENR-GE) composites with segregated GE networks were successfully fabricated using the latex mixing combined in situ reduced technology. The rheological behavior and electrical conductivity of ENR-GE composites were investigated. At low frequencies, the storage modulus (G') became frequency-independent suggesting a solid-like rheological behavior and the formation of GE networks. According to the percolation theory, the rheological threshold of ENR-GE composites was calculated to be 0.17 vol%, which was lower than the electrical threshold of 0.23 vol%. Both percolation thresholds depended on the evolution of the GE networks in the composites. At low GE concentrations (<0.17 vol%), GE existed as individual units, while a "polymer-bridged GE network" was constructed in the composites when GE concentrations exceeded 0.17 vol%. Finally, a "three-dimensional GE network" with percolation conductive paths was formed with a GE concentration of 0.23 vol%, where a remarkable increase in the conductivity of ENR-GE composites was observed. The effect of GE on the atom scale free-volume properties of composites was further studied by positron annihilation lifetime spectroscopy and positron age momentum correlation measurements. The motion of ENR chains was retarded by the geometric confinement of "GE networks", producing a high-density interfacial region in the vicinity of GE nanoplatelets, which led to a lower ortho-positronium lifetime intensity and smaller free-volume hole size.