A smart hybrid nanowire array consisting of Co3O4 porous nanowire core and a MnO2 ultrathin nanosheet shell is fabricated using a general 3D interfacial carbon‐assisted hydrothermal method. The array exhibits a high capacitance with good cycle performance and remarkable rate capability that is ranging among the best reported to date for hybrid metal oxide systems in the absence of a conducting matrix.
We report the properties of a field effect transistor (FET) and a gas sensor based on CuO nanowires. CuO nanowire FETs exhibit p-type behavior. Large-scale p-type CuO nanowire thin-film transistors (10(4) devices in a 25 mm(2) area) are fabricated and we effectively demonstrate their enhanced performance. Furthermore, CuO nanowire exhibits high and fast response to CO gas at 200 degrees C, which makes it a promising candidate for a poisonous gas sensing nanodevice.
Hierarchical nanostructures with SnO(2) backbones and ZnO branches are successfully prepared in a large scale by combining the vapor transport and deposition process (for SnO(2) nanowires) and a hydrothermal growth (for ZnO). The ZnO nanorods grow epitaxially on the SnO(2) nanowire side faces mainly with a four-fold symmetry. The number density and morphology of the secondary ZnO can be tailored by changing the precursor concentration, reaction time, and by adding surfactants. Photoluminescence (PL) properties are studied as a function of temperature and pumping power. Such hybrid SnO(2)-ZnO nanostructures show an enhanced near-band gap emission compared with the primary SnO(2) nanowires. Under the optical excitation, a UV random lasing is observed which originates from the hierarchically assembled ZnO branches. These three-dimensional nanostructures may have application potentials as chemical sensors, battery electrodes, and optoelectronic devices.
Truncated octahedral (TO) Ag nanoparticles are subjected to a replacement reaction with HAuCl4, where they undergo a series of morphological changes to transform into Ag@AgAu metal core/alloy shell nanoparticles (see image). In the final stage, atomic rearrangement occurrs to restore the bimetallic particles to the initial TO shape.
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