Organic-inorganic halide perovskite-based thin film solar cells show excellent light-to-power conversion efficiency. The high performance for the devices requires the preparation of well-crystallized perovskite absorbers. In this paper, we used the postannealing process to treat the perovskite films under different solvent vapors and observed that the solvent vapors have a strong effect on the film growth. A model regarding the perovskite film growth was proposed as well. Intensive characterizations including scanning electron microscopy, electrochemical impedance spectroscopy, and admittance spectroscopy allowed us to attribute the improved performance to reduced recombination loss and defect density. Solar cell based on the DMSO-treated films delivered a power conversion efficiency of over 13% with negligible photocurrent hysteresis.

Abstract. Over past decades, a lot of global land-cover products have been released; however, these still lack a global land-cover map with a fine classification system and spatial resolution simultaneously. In this study, a novel global 30 m land-cover classification with a fine classification system for the year 2015 (GLC_FCS30-2015) was produced by combining time series of Landsat imagery and high-quality training data from the GSPECLib (Global Spatial Temporal Spectra Library) on the Google Earth Engine computing platform. First, the global training data from the GSPECLib were developed by applying a series of rigorous filters to the CCI_LC (Climate Change Initiative Global Land Cover) land-cover and MCD43A4 NBAR products (MODIS Nadir Bidirectional Reflectance Distribution Function-Adjusted Reflectance). Secondly, a local adaptive random forest model was built for each 5∘×5∘ geographical tile by using the multi-temporal Landsat spectral and texture features and the corresponding training data, and the GLC_FCS30-2015 land-cover product containing 30 land-cover types was generated for each tile. Lastly, the GLC_FCS30-2015 was validated using three different validation systems (containing different land-cover details) using 44 043 validation samples. The validation results indicated that the GLC_FCS30-2015 achieved an overall accuracy of 82.5 % and a kappa coefficient of 0.784 for the level-0 validation system (9 basic land-cover types), an overall accuracy of 71.4 % and kappa coefficient of 0.686 for the UN-LCCS (United Nations Land Cover Classification System) level-1 system (16 LCCS land-cover types), and an overall accuracy of 68.7 % and kappa coefficient of 0.662 for the UN-LCCS level-2 system (24 fine land-cover types). The comparisons against other land-cover products (CCI_LC, MCD12Q1, FROM_GLC, and GlobeLand30) indicated that GLC_FCS30-2015 provides more spatial details than CCI_LC-2015 and MCD12Q1-2015 and a greater diversity of land-cover types than FROM_GLC-2015 and GlobeLand30-2010. They also showed that GLC_FCS30-2015 achieved the best overall accuracy of 82.5 % against FROM_GLC-2015 of 59.1 % and GlobeLand30-2010 of 75.9 %. Therefore, it is concluded that the GLC_FCS30-2015 product is the first global land-cover dataset that provides a fine classification system (containing 16 global LCCS land-cover types as well as 14 detailed and regional land-cover types) with high classification accuracy at 30 m. The GLC_FCS30-2015 global land-cover products produced in this paper are free access at https://doi.org/10.5281/zenodo.3986872 (Liu et al., 2020).

Low-temperature, solution processed metal sulfide is introduced as an electron transport layer for perovskite solar cells.