Transparent, UV-filtered, anti-freezing, and moisture-retention organohydrogel-based sensors are prepared by incorporating ions/microparticles into a binary solvent system.
An anti-freezing and moisturizing conductive hydrogel, capable of harvesting energy from moisture, was developed by incorporating tannic acid and carbon nanotubes into polyvinyl alcohol containing a water–glycerol dispersion.
Recently, flexible,
injectable, and strain-sensitive hydrogels
have attracted great research interest for application as electronic
skin and wearable strain sensors. The synergistic integration of high
flexibility, rapid self-healing, and antifreezing properties makes
injectable, strain-sensitive, and self-healing guar gum hydrogels
still a great challenge. Here, inspired by the strong hydrogen bonding
of glycerol and water, the chelation cross-linking between glycerol
and borax, we constructed a compact three-dimensional dynamic cross-linked
net formed of glycerol–water–borax. Under stress, dynamic
interactions of glycerol–water–borax net act as sacrificial
bond energy for effective dissipation, which enables the hydrogel
to achieve high flexibility, stretchability, and injectability. More
importantly,because of the presence of glycerol, the antifreeze and
moisturizing properties of the gel are improved. The hydrogel also
exhibited an ultrafast self-healing ability of only 15 s. In addition,
the results show that the hydrogel has self-adhesive properties and
strain sensitivity. The hydrogels have the potential to be used to
make flexible, wearable, and 3D-printable electronic skin and strain-sensitive
sensors.
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