The production of intermediate mass fragments ͑IMF's͒ from the four reactions 55A MeV 124,136 Xe ϩ 112,124 Sn is studied with an experimental apparatus which is highly efficient for the detection of both charged particles and neutrons. The IMF's are more localized in the midvelocity region than are the light charged particles, and the detected multiplicity of IMF's depends linearly on the charge lost from the projectile and increases with the neutron excess of the system. Remnants of the projectile, with very little velocity reduction, are found for most of the reaction cross section. Isotopic and isobaric fragment yields in the projectile-velocity region indicate that charge-to-mass ratio neutralization is generally not achieved but is approached when little remains of the projectile. For all systems, the fragments found in the midvelocity region are substantially more neutron rich than those found in the velocity region dominated by the emission from the projectile. This observation can be accounted for if the midvelocity source ͑or sources͒ is either more neutron rich or smaller, with the same neutron-to-proton ratio, than the source with the velocity of the projectile. Taken together, the observations of this work suggest that the intermediate mass fragments are, to a large extent, formed by multiple neck rupture of the overlap material, a process which might enhance the neutron-to-proton ratio of the primary source material and/or limit the size of the sources. This scenario is reminiscent of low-energy ternary fission and one predicted by Boltzmann-Uehling-Uhlenbeck calculations. However, these calculations predict too much velocity damping of the projectile remnant. The calculations improve, in this regard, when the in-medium nucleon-nucleon cross sections and the cost of creating low density material are reduced.

Multifragment disintegrations, measured for central Au + Au collisions at E/A = 35M eV , are analyzed with the Statistical Multifragmentation Model. Charge distributions, mean fragment energies, and two-fragment correlation functions are well reproduced by the statistical breakup of a large, diluted and thermalized system slightly above the multifragmentation threshold.

Adsorption involves molecules colliding at the surface of a solid and losing their incidence energy by traversing a dynamical pathway to equilibrium. The interactions responsible for energy loss generally include both chemical bond formation (chemisorption) and nonbonding interactions (physisorption). In this work, we present experiments that revealed a quantitative energy landscape and the microscopic pathways underlying a molecule’s equilibration with a surface in a prototypical system: CO adsorption on Au(111). Although the minimum energy state was physisorbed, initial capture of the gas-phase molecule, dosed with an energetic molecular beam, was into a metastable chemisorption state. Subsequent thermal decay of the chemisorbed state led molecules to the physisorption minimum. We found, through detailed balance, that thermal adsorption into both binding states was important at all temperatures.