In solution‐processable small molecule semiconductors, the extent of charge carrier wavefunction localization induced by dynamic disorder can be probed spectroscopically as a function of temperature using charge modulation spectroscopy (CMS). Here, it is shown based on combined field‐effect transistor and CMS measurements as a function of temperature that in certain molecular semiconductors, such as solution‐processible pentacene, charge carriers become trapped at low temperatures in environments in which the charges become highly localized on individual molecules, while in some other molecules the charge carrier wavefunction can retain a degree of delocalization similar to what is present at room temperature. The experimental approach sheds new insight into the nature of shallow charge traps in these materials and allows identifying molecular systems in which intrinsic transport properties could, in principle, be observed at low temperatures if other transport bottlenecks associated with grain boundaries or contacts could be removed.
Realising bright and vivid full colour performance in electrophoretic displays presents a significant challenge to display architects and material designers. A range of dyed polymeric microparticles with tunable size, charge and colour have been developed. When formulated as colloidal dispersions in low dielectric constant media, the particles are electrophoretically active and are suitable for use in full colour or monochrome electrophoretic displays.
We present Merck's new formulation and material developments enabling high‐volume and high‐throughput printing techniques to be used for cost‐effective electronic circuitry and backplane production. Performance at TFT array level in excess of 2 cm2/Vs, comparable to spin coating is demonstrated at Gen1 scale and 50 ppi resolution, using a hybrid combination of conventional lithographic steps and direct gravure printing.
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