A series of six new free base porphyrins were synthesized for use as photosensitizers in TiO 2 dye-sensitized photo-electrochemical cells. The porphyrin sensitizers are attached to the TiO 2 photoelectrode by phosphonic or carboxylic acid anchoring groups. These anchoring groups were placed on different substitution positions on the porphyrin moiety. The new dyes were fully characterized by absorption and emission spectroscopies, electrochemistry and photo-electrochemical spectroscopy. The photo-electrochemical performances of the sensitizers are discussed and compared to the known 5,10,15,20-tetra(4-carboxyphenyl)porphyrin sensitizer. In this study, we show that the nature of the anchoring group (phosphonic or carboxylic acids) has little impact on the photo-electrochemical performance of the cell. However, the substitution position of the anchoring group on the porphyrin strongly influences the monochromatic photon-to-electron conversion efficiency of the resulting cell. The results indicate that the electronic coupling of this type of dye with the d-band of the semiconductor is one of the key parameters in the design of efficient sensitizers.

International audienceCuGaO2 is used here as photocathode in place of NiO for a p-type dye-sensitized solar cell with iodide/triiodide (I-/I-3(-)) or tris(4,4'-bis-tert-butyl-2,2'-bipyridine) cobalt (Co2+/Co3+) as redox mediator, and PMI or PMI-NDI as sensitizer. Both photovoltaic characteristics and flat band potentials suggest that CuGaO2 can be viewed as a promising substitute for NiO

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