Bimetallic Cu−Ni/TiO 2 photocatalysts were prepared at different temperatures with varying Cu:Ni mass compositions. The photocatalysts were further calcined at selected temperatures. Characterization procedures were carried out on the photocatalysts to understand the correlation between the photocatalytic activity and the physicochemical and morphological properties. Results from the XRD, FESEM-EDX mapping, and HRTEM analyses were in favor of the metal particles existing in the form of well-dispersed oxides on TiO 2 surface. The surface area of the photocatalysts was almost similar to the bare TiO 2 ∼43 m 2 g −1 except for 1Cu:9Ni-200-b observed with a higher surface area (53.8 m 2 g −1 ) as compared to other photocatalysts. The photocatalyst performance of the bimetallic system is promising as compared to bare TiO 2 and the monometallic photocatalysts. Results for photodegradation studies showed that 1:9 Cu:Ni mass composition was observed with 100% Orange II removal as compared to other Cu:Ni mass compositions. The 1Cu:9Ni-200-a photocatalyst prepared at lower temperature (8−10 °C) displayed 100% Orange II decolorization as compared to 1Cu:9Ni-200-b (prepared at higher temperature of 25 °C) with 65.1% dye removal. Although the results from UV−vis spectra showed the disappearance of the visible band (indicating 100% Orange II removal), TOC analysis indicated the presence of organic compounds derived from the dye degradation process. Therefore, longer irradiation time is required to break the chromophore groups in the degradation intermediates to obtain 100% TOC removal.
Waste wood biomass as precursor for manufacturing activated carbon (AC) can provide a solution to ever increasing global water quality concerns. In our current work, Melia azedarach derived phosphoric acid-treated AC (MA-AC400) was manufactured at a laboratory scale. This novel MA-AC400 was tested for RO16 dye removal performance as a function of contact time, adsorbent dosage, pH, temperature and initial dye concentration in a batch scale arrangement. MA-AC400 was characterized via scanning electron microscopy, energy dispersive X-ray spectroscopy, Fourier transform infrared spectroscopy, dynamic light scattering (DLS) and fluorescence spectroscopy. MA-AC400 is characterized as mesoporous with BET surface area of 293.13 m2 g−1 and average pore width of 20.33 Å. pHPZC and Boehm titration confirm the acidic surface charges with dominance of phenolic functional groups. The average DLS particle size of MA-AC400 was found in the narrow range of 0.12 to 0.30 µm and this polydispersity was confirmed with multiple excitation fluorescence wavelengths. MA-AC400 showed equilibrium adsorption efficiency of 97.8% for RO16 dye at its initial concentration of 30 mg L−1 and adsorbent dose of 1 g L−1. Thermodynamic study endorsed the spontaneous, favorable, irreversible and exothermic process for RO16 adsorption onto MA-AC400. Equilibrium adsorption data was better explained by Langmuir with high goodness of fit (R2, 0.9964) and this fitness was endorsed with lower error functions. The kinetics data was found well fitted to pseudo-second order (PSO), and intra-particle diffusion kinetic models. Increasing diffusion constant values confirm the intraparticle diffusion at higher RO16 initial concentration and reverse was true for PSO chemisorption kinetics. MA-AC400 exhibited low desorption with studied eluents and its cost was calculated to be $8.36/kg.
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