Through transport, compositional and structural studies, we review the features of the chargedensity wave (CDW) conductor of NbS3 (phase II). We highlight three central results: 1) In addition to the previously reported CDW transitions at TP 1 = 360 K and TP 2 = 150 K, another CDW transition occurs at a much higher temperature TP 0 = 620-650 K; evidence for the non-linear conductivity of this CDW is presented. 2) We show that CDW associated with the TP 2 -transition arises from S vacancies acting as donors. Such a CDW transition has not been observed before. 3) We show exceptional coherence of the TP 1-CDW at room-temperature. Additionally, we report on the effects of uniaxial strain on the CDW transition temperatures and transport.
The new phase of YbAg 2 was obtained using high-pressure and high-temperature reaction. YbAg 2 crystallizes in the MgZn 2 structure (the space group P6 3 /mmc space group, № 194) with a = 5.68153(3) Å and c = 9.31995(7)Å and the unit cell volume V = 260.54(3) Å 3. The XANES analysis showed that the valence state of Yb is +2.8. The low-temperature dependences of the electrical resistivity and magnetic susceptibility can be adequately described by a T 2 term that supports the Fermi-liquid picture. The Kadowaki-Woods relation gives a low value of the degeneracy (N = 2).
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