In order to obtain bioenergy (biogas, biofuel) or pellets, different types of lignocellulosic biomass are subjected to a mechanical pretreatment, first by size reduction, then by separating, and ultimately by fracturing or bio-refining. Biomass processing mainly refers to a grinding process that occurs until reaching certain limits. The size reduction process, such as grinding, is an operation that is executed with different levels of energy consumption, considering biomass mechanical characteristics and the necessary grinding level. This paper, illustrates a comparative analysis of experimental results obtained by grinding multiple types of vegetal biomass (Miscanthus, corn stalks, alfalfa, willow) used in the process of bio-refining and bio-fracturing. Experiments were realized using both a laboratory knife mill Grindomix GM200 (Retsch GmbH, Haan, Germany), and a 22 kW articulated hammer mill, using different grinding system speeds and different hammer mill sieves. Results have shown that biomass mechanical pre-processing grinding leads to supplementary costs in the overall process through bio-refining or bio-fracturing in order to obtain bio-products or bio-energy. So, specific energy consumption for grinding using a hammer mill can reach 50–65 kJ/kg for harvested Miscanthus biomass, and 35–50 kJ/kg for dried energetic willow, using a 10 mm orifice sieve, values which increase processing costs.

The aim of this article is to present a nonconventional method for the efficient removal of lead ions from industrial wastewater. For this purpose, magnetite nanomaterial was used, which was very easily separated from the wastewater at the end of the treatment due to its magnetic properties. Currently, nanotechnology is an efficient and inexpensive manner that is being researched for wastewater treatment. Additionally, iron oxide nanoparticles are widely used to remove heavy metal ions from water due to their special properties. The experimental results detailed in this article show the influence of pH and contact time on the process of adsorption of lead ions from wastewater. The magnetite nanomaterial had its maximum efficiency of speed when the wastewater had pH 6. At a lower pH, the highest treatment efficiency was over 85%, and the required contact time has doubled. When the pH increases above 6, the precipitation process occurs. Langmuir and Freundlich models were used to describe the adsorption process.

This paper presents theoretical and experimental research studying the influence of process parameters on the quality of biomass pellets. A validated mathematical model was developed, expressing the density of biomass pellets as determined by moisture content, compression pressure, process heat, the initial density of the material, pelleting speed and initial volume of the material. The experiments for determining the influence of these parameters on the compression of biomass into pellets and optimizing the process were conducted on a heated single pellet compression device, using fir sawdust as raw material. To describe and study the process, four input and control parameters were varied—raw material moisture, pelleting speed, maximum force applied and pelleting die temperature. From the experiments, it was noticed that overall, moisture and pressure have the most important effect on the compression process and pelleting speed, and heat applied also affected the process. Pellet density decreased when pelleting speed and material moisture increase and the density increased with a higher compression pressure and higher heat during the process.

From the available statistical data, cement factories co-process a range of over 100 types of waste (sorted both industrial and household) being authorized for their use as combustion components in clinker ovens. Therefore, the level of emissions is different depending on the type of fuels and waste used. The amount of industrial and municipal co-processed waste in the Romanian cement industry from 2004 to 2013 was about 1,500,000 tons, the equivalent of municipal waste generated in a year for 18 cities with over 250,000 inhabitants. The objective of this paper was to evaluate the emission level of hydrochloric acid (HCl) and hydrofluoric acid (HF) at the clinker kilns at two cement factories in Romania for different annual time intervals and to do a comparative analysis, to estimate their compliance with legislation in force. The measurements results showed average emission levels of about 0.578 mg/Nm3 for HCl and about 0.100 mg/Nm3 for HF, in the first hours of the evening, but decreased at the beginning of the third tour, at about 0.385 mg/Nm3 for HCl, respectively, to about 0.085 mg/Nm3 for HF. The evolution of HCl and HF emission levels during the last 4 years showed a variable distribution of these acids.

Our paper presents the hammer mill working process optimization problem destined for milling energetic biomass (MiscanthusGiganteus and Salix Viminalis). For the study, functional and constructive parameters of the hammer mill were taken into consideration in order to reduce the specific energy consumption. The energy consumption dependency on the mill rotor spinning frequency and on the sieve orifices in use, as well as on the material feeding flow, in correlation with the vegetal biomass milling degree was the focus of the analysis. For obtaining this the hammer mill was successively equipped with 4 different types of hammers that grind the energetic biomass, which had a certain humidity content and an initial degree of reduction ratio of the material. In order to start the optimization process of hammer mill working process, 12 parameters were defined. The objective functions which minimize hammer mill energy consumption and maximize the milled material percentage with a certain specific granulation were established. The results obtained can serve as the basis for choosing the optimal working, constructive, and functional parameters of hammer mills in this field, and for a better design of future hammer mills.