TiO2 nanotubes were successfully synthesized by electrochemical method. A fluoride salt mixture was used as an electrolyte for synthesizing TiO2 nanotubes on titanium substrates. In this work, we have reported the synthesis procedure of TiO2 nanotubes and investigated the corrosion resistance of TiO2 nanotubes coated on the Ti substrate. FE-SEM was used to observe the morphology and determine the size of the TiO2 nanotubes. The phase formation and crystal quality of TiO2 nanotubes were studied by XRD measurements. One-microliter distilled water droplets were used to define the wettability of the TiO2 nanotube surfaces by measuring the contact angle. The corrosion resistance behavior of specimens was analyzed in the simulated body fluid solution (SBF) using potentiodynamic polarization tests for potential application as implants.
Hydroxyapatite (HAp) has been successfully coated on etched titanium substrates by hydrothermal method using solutions of Ca(NO3)2.4H2O, NH4H2PO4 at 200 oC for 12 h. Results obtained from measurements on the modern physical methods of FE-SEM and XRD showedhat the structure of HAp has a regular hexagonal morphology belonging to the space group P63/m. The degree of HAp nucleation and nucleation development on the un-etched titanium plates was lower than that on the etched titanium plates. In vitro bioactivity of HAp-coated titanium testing using SBF solution showed prospective results.
Keywords: Hydroxyapatite (HAp), Hydrothermal method, etched, titanium.
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