All planetary materials sampled thus far vary in their relative abundance of the major isotope of oxygen, (16)O, such that it has not been possible to define a primordial solar system composition. We measured the oxygen isotopic composition of solar wind captured and returned to Earth by NASA's Genesis mission. Our results demonstrate that the Sun is highly enriched in (16)O relative to the Earth, Moon, Mars, and bulk meteorites. Because the solar photosphere preserves the average isotopic composition of the solar system for elements heavier than lithium, we conclude that essentially all rocky materials in the inner solar system were enriched in (17)O and (18)O, relative to (16)O, by ~7%, probably via non-mass-dependent chemistry before accretion of the first planetesimals.

Abstract. Improved versions of Lunar Prospector thermal and epithermal neutron data were studied to help discriminate between potential delivery and retention mechanisms for hydrogen on the Moon. Improved spatial resolution at both poles shows that the largest concentrations of hydrogen overlay regions in permanent shade. In the north these regions consist of a heavily cratered terrain containing many small (less than -10-km diameter), isolated craters. These border circular areas of hydrogen abundance ([H]) that is only modestly enhanced above the average equatorial value but that falls within large, flatbottomed, and sunlit polar craters. Near the south pole, [HI is enhanced within several 30-km-scale craters that are in permanent shade but is only modestly enhanced within their sunlit neighbors. We show that delivery by the solar wind cannot account for these observations because the diffusivity of hydrogen at the temperatures within both sunlit and permanently shaded craters near both poles is sufficiently low that a solar wind origin cannot explain their differences. We conclude that a significant portion of the enhanced hydrogen near both poles is most likely in the form of water molecules.

We compare element and isotopic fractionations measured in bulk solar wind samples collected by NASA's Genesis mission with those predicted from models incorporating both the ponderomotive force in the chromosphere and conservation of the first adiabatic invariant in the low corona. Generally good agreement is found, suggesting that these factors are consistent with the process of solar wind fractionation. Based on bulk wind measurements, we also consider in more detail the isotopic and elemental abundances of O. We find mild support for an O abundance in the range 8. 75-8.83, with a value as low as 8.69 disfavored. A stronger conclusion must await solar wind regime-specific measurements from the Genesis samples.

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