No abstract

A method is introduced to determine notch toughness of bulk metallic glasses (BMGs). Through thermoplastic replication of Si molds, unprece-10 dented control in fabricating BMG toughness samples can be achieved and influences such as cooling rate, thermal history, residual stress, sample geometry, and notch precision are drastically reduced. For the 20 Zr 44 Ti 11 Cu 10 Ni 10 Be 25 BMG samples, we measured a notch toughness of 109 ± 3 MPa ffiffiffi ffi m p . Such a much smaller scatter than the previously reported suggests reliable properties of BMGs when thermoplastically formed.

3D Metallic glass structures (3DMGs) are fabricated through thermoplastic forming (TPF)-based patterning of MG sheets combined with a parallel joining technique. To demonstrate this capability and benchmark 3DMGs, we have fabricated honeycomb-like MG architectures covering a wide range of relative densities. 3DMGs exhibit high elasticity of up to 40% loading strain, high elastic energy storability, and high energy absorption which is superior compared to those made from other materials such as conventional metals and ceramics, based on our theoretical analysis. The combination of MG properties and introduced versatile fabrication method suggest the possibility of developing a wide range of 3DMGs with excellent performance for specific applications.

The flaw tolerance of bulk metallic glasses (BMGs) is evaluated using a thermoplastic synthesis approach. We found that flaw tolerance quantified by the notch toughness decreases apparently with decreasing radius until a critical value. Below this critical value, measured notch toughness is independent of its radius, revealing a flaw tolerance behavior of BMGs. We explain such flaw tolerance by a critical plastic zone originating from the BMGs' inherent crack tip blunting capability. This zone defines a characteristic distance over which stable shear banding plastic process develops prior to fracture instability. The specific characteristic distance and crack blunting capability vary widely among BMGs, which rationalizes the vast variety in their fracture behavior and suggest specific flaw tolerance. Our finding is encouraging for BMGs' structural applications since flaws smaller than the critical value are increasingly difficult to avoid but are "indistinguishable" in their influence to fracture toughness.

Direct measurement of critical cooling rates has been challenging and only determined for a minute fraction of the reported metallic glass forming alloys. Here, we report a method that directly measures critical cooling rate of thin film metallic glass forming alloys in a combinatorial fashion. Based on a universal heating architecture using indirect laser heating and a microstructure analysis this method offers itself as a rapid screening technique to quantify glass forming ability. We use this method to identify glass forming alloys and study the composition effect on the critical cooling rate in the Al–Ni–Ge system where we identified Al51Ge35Ni14 as the best glass forming composition with a critical cooling rate of 104 K/s.