Hydrogen peroxide (H2O2), an important industrial chemical, is currently produced through an energy-intensive anthraquinone process that is limited to large-scale facilities. Small-scale decentralized electrochemical production of H2O2 via a two-electron oxygen reduction reaction (ORR) offers unique opportunities for sanitization applications and the purification of drinking water. The development of inexpensive, efficient, and selective catalysts for this reaction remains a challenge. Herein, we examine two different porous carbon-based electrocatalysts and show that they exhibit high selectivity for H2O2 under alkaline conditions. By rationally varying synthetic methods, we explore the effect of pore size on electrocatalytic performance. Furthermore, by means of density functional calculations, we point out the critical role of carbon defects. Our theory results show that the majority of defects in graphene are naturally selective for the two-electron reduction of O2 to H2O2, and we identify the types of defects with high activity.

To limit further rising levels in methane emissions from stationary and mobile sources and to enable promising technologies based on methane, the development of efficient combustion catalysts that completely oxidize CH4 to CO2 and H2O at low temperatures in the presence of high steam concentrations is required. Palladium is widely considered as one of the most promising materials for this reaction, and a better understanding of the factors affecting its activity and stability is crucial to design even more improved catalysts that efficiently utilize this precious metal. Here we report a study of the effect of three important variables (particle size, support, and reaction conditions including water) on the activity of supported Pd catalysts. We use uniform palladium nanocrystals as catalyst precursors to prepare a library of well-defined catalysts to systematically describe structure–property relationships with help from theory and in situ X-ray absorption spectroscopy. With this approach, we confirm that PdO is the most active phase and that small differences in reaction rates as a function of size are likely due to variations in the surface crystal structure. We further demonstrate that the support exerts a limited influence on the PdO activity, with inert (SiO2), acidic (Al2O3), and redox-active (Ce0.8Zr0.2O2) supports providing similar rates, while basic (MgO) supports show remarkably lower activity. Finally, we show that the introduction of steam leads to a considerable decrease in rates that is due to coverage effects, rather than structural and/or phase changes. Altogether, the data suggest that to further increase the activity and stability of Pd-based catalysts for methane combustion, increasing the surface area of supported PdO phases while avoiding strong adsorption of water on the catalytic surfaces is required. This study clarifies contrasting reports in the literature about the active phase and stability of Pd-based materials for methane combustion.

We describe the RESIK (REntgenovsky Spektrometr s Izognutymi Kristalami) instrument, consisting of two double-channel X-ray spectrometers, designed to observe solar active region and flare plasmas. RESIK is one of the instruments making up the scientific payload of the Russian CORONAS-F solar mission. The uncollimated spectrometer uses two silicon and two quartz bent crystals observing flare, active region and coronal spectra in four wavelength bands with a resolving power (λ/ λ) of ∼1000. The wavelength coverage, 3.3 -6.1Å, includes emission lines of Si, S, Cl, Ar, and K and in the third diffraction order, the wavelength range includes He-like Fe lines (1.85Å) and Ni lines (1.55Å) with dielectronic satellites, emitted during intense, hot flares. The instrument is believed to be the best calibrated space-borne crystal spectrometer flown to date. The spectrometer dynamically adjusts the data gathering intervals from 1 s to 5 minutes, depending on the level of solar X-ray emission at the time of observation. The principal aims of RESIK are the measurements of relative and absolute element abundances in the emitting plasma and the temperature distribution of plasma (differential emission measure) over the temperature interval 3 and 50 MK. This paper summarizes the scientific objectives of RESIK and describes the design, characteristics, and performance of the instrument.