Cold atoms with laser-induced spin-orbit (SO) interactions provide intriguing new platforms to explore novel quantum physics beyond natural conditions of solids. Recent experiments demonstrated the one-dimensional (1D) SO coupling for boson and fermion gases. However, realization of 2D SO interaction, a much more important task, remains very challenging.Here we propose and experimentally realize, for the first time, 2D SO coupling and topological band with 87 Rb degenerate gas through a minimal optical Raman lattice scheme, without relying on phase locking or fine tuning of optical potentials. A controllable crossover between 2D and 1D SO couplings is studied, and the SO effects and nontrivial band topology are observed by measuring the atomic cloud distribution and spin texture in the momentum 1 arXiv:1511.08170v1 [cond-mat.quant-gas] 24 Nov 2015space. Our realization of 2D SO coupling with advantages of small heating and topological stability opens a broad avenue in cold atoms to study exotic quantum phases, including the highly-sought-after topological superfluid phases.Spin-orbit (SO) interaction of an electron is a relativistic quantum mechanic effect, which characterizes the coupling between motion and spin of the electron when moving in an electric field. In the rest frame the electron experiences a magnetic field which is proportional to the electron velocity and couples to its spin by the magnetic dipole interaction, rendering the SO coupling. The SO interaction plays essential roles in many novel quantum states of solids. The recent outstanding examples include the topological insulators, which have been predicted and experimentally discovered in two-dimensional (2D) and 3D materials 1, 2 , and the topological superconductors 3, 4 , which host exotic zero-energy states called Majorana fermions 5,6 and still necessitate rigorous experimental verification. For topological insulators, the strong SO interaction leads to the so-called band inversion mechanism which drives a topological phase transition in such systems 7,8 . In superconductors, a triplet p-wave pairing is generically resulted when SO coupling is present, for which the superconductivity can be topologically nontrivial under proper conditions 9 .Recently, considerable interests have been drawn in emulating SO effects and topological phases with cold atoms, mostly driven by the fact that cold atoms can offer extremely clean platforms with full controllability to explore such exotic physics. In cold atoms the synthetic SO interaction can be generated by Raman coupling schemes which flip atom spins and transfer momentum where 1 is the 2 × 2 unit matrix, σ x,y,z are Pauli matrices acting on the spins, m is mass of an atom, V latt denotes the lattice potential in the x-z plane, M x,y are periodic Raman coupling potentials, and m z represents a tunable Zeeman field. Atoms can hop between nearest-neighboring sites due to lattice potential as well as the Raman coupling terms. Note that V latt is spin-independent and can induce hopping which conserves ...

Unique spindle-shaped nanoporous anatase TiO(2) mesocrystals with a single-crystal-like structure and tunable sizes were successfully fabricated on a large scale through mesoscale assembly in the tetrabutyl titanate-acetic acid system without any additives under solvothermal conditions. A complex mesoscale assembly process involving slow release of soluble species from metastable solid precursors for the continuous formation of nascent anatase nanocrystals, oriented aggregation of tiny anatase nanocrystals, and entrapment of in situ produced butyl acetate as a porogen was put forward for the formation of the anatase mesocrystals. It was revealed that the acetic acid molecules played multiple key roles during the nonhydrolytic processing of the [001]-oriented, single-crystal-like anatase mesocrystals. The obtained nanoporous anatase mesocrystals exhibited remarkable crystalline-phase stability (i.e., the pure phase of anatase can be retained after being annealed at 900 °C) and improved performance as anode materials for lithium ion batteries, which could be largely attributed to the intrinsic single-crystal-like nature as well as high porosity of the nanoporous mesocrystals.