Operando X-ray absorption spectroscopy (XAS) technique unravels that the CoFe nanoparticles in a new type of lanthana-anchored CoFe catalyst are nearly transformed into unique (Co/Fe)O(OH) under the electrochemical condition, as real active species for oxygen evolution reaction.

Water electrolysis is promising for industrial hydrogen production to achieve a sustainable and green hydrogen economy, but the high cost of the technology limits its market share. Developing efficient yet economic electrocatalysts is crucial to decrease the cost of electricity and electrolytic cell. Meanwhile, electrolysis in seawater electrolyte can further reduce feedstock cost. Here, a type of electrocatalyst is synthesized, where trace precious metals are strongly anchored on a corrosion-resistive matrix. As an example, the produced Pt/Ni-Mo electrocatalyst only needs an overpotential of 113 mV to reach an ultrahigh current density of 2000 mA cm −2 in the saline-alkaline electrolyte, demonstrating the best performance reported thus far. It shows high activity and long durability in various electrolytes and under harsh conditions, including strong alkaline and simulated seawater electrolytes, and under elevated temperatures up to 80 °C. This electrocatalyst is produced on a large scale at a low cost and shows good performance in a commercial membrane electrode assembly stack, demonstrating its feasibility for practical water electrolysis.

We present a spectroscopic catalog of 58,360 M dwarfs from the Large Sky Area Multi-Object Fiber Spectroscopic Telescope pilot survey. For each spectrum in the catalog, spectral subtype, radial velocity, Hα equivalent width, a number of prominent molecular band indices, and the metal-sensitive parameter ζ are provided. We use the Sloan Digital Sky Survey Data Release 7 Spectroscopic M dwarf catalog to verify the precision of our methods of classifying the spectral types and measuring the radial velocities. The magnetic activity properties of M dwarfs are also traced by Hα emission lines. The molecular band indices included in this catalog are sensitive to temperature or metallicity, and can be used for further study of the physical properties of M dwarfs. This M dwarf catalog is available on the Web site http://sciwiki.lamost.org/MCatalogPilot/.