The recovery of a modulated magnetic structure in epitaxial BiFeO 3 thin fi lms as revealed by neutron diffraction is reported. The magnetic structure in thin fi lms is found to strongly depend on substrate orientation. The substrate orientation causes different strain-relaxation processes resulting in different thin-fi lm crystal structures. The (110) oriented fi lm with a monoclinic structural phase has a single-domain modulated magnetic structure where the magnetic moment lies in the HHL plane. For the (111) oriented fi lm that has a rhombohedral structure, a modulated structure superimposed on the G-type antiferromagnetic order is found. These results indicate that slight structural modifi cations in the BiFeO 3 thin fi lm cause drastic changes in the magnetic structure.
MnP, a superconductor under pressure, exhibits a ferromagnetic order below
TC~290 K followed by a helical order with the spins lying in the ab plane and
the helical rotation propagating along the c axis below Ts~50 K at ambient
pressure. We performed single crystal neutron diffraction experiments to
determine the magnetic ground states under pressure. Both TC and Ts are
gradually suppressed with increasing pressure and the helical order disappears
at ~1.2 GPa. At intermediate pressures of 1.8 and 2.0 GPa, the ferromagnetic
order first develops and changes to a conical or two-phase (ferromagnetic and
helical) structure with the propagation along the b axis below a characteristic
temperature. At 3.8 GPa, a helical magnetic order appears below 208 K, which
hosts the spins in the ac plane and the propagation along the b axis. The
period of this b axis modulation is shorter than that at 1.8 GPa. Our results
indicate that the magnetic phase in the vicinity of the superconducting phase
may have a helical magnetic correlation along the b axis.Comment: 5 pages, 4 figure
Thermoelectrics are promising by directly generating electricity from waste heat. However, (sub-)room-temperature thermoelectrics have been a long-standing challenge due to vanishing electronic entropy at low temperatures. Topological materials offer a new avenue for energy harvesting applications. Recent theories predicted that topological semimetals at the quantum limit can lead to a large, non-saturating thermopower and a quantized thermoelectric Hall conductivity approaching a universal value. Here, we experimentally demonstrate the non-saturating thermopower and quantized thermoelectric Hall effect in the topological Weyl semimetal (WSM) tantalum phosphide (TaP). An ultrahigh longitudinal thermopower $$S_{xx} \sim 1.1 \times 10^3 \, \mu \, {\mathrm{V}} \, {\mathrm{K}}^{ - 1}$$
S
x
x
~
1.1
×
1
0
3
μ
V
K
−
1
and giant power factor $$\sim 525 \, \mu \, {\mathrm{W}} \, {\mathrm{cm}}^{ - 1} \, {\mathrm{K}}^{ - 2}$$
~
525
μ
W
cm
−
1
K
−
2
are observed at ~40 K, which is largely attributed to the quantized thermoelectric Hall effect. Our work highlights the unique quantized thermoelectric Hall effect realized in a WSM toward low-temperature energy harvesting applications.
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