We present precision Penning trap mass measurements of neutron-rich calcium and potassium isotopes in the vicinity of neutron number N=32. Using the TITAN system, the mass of ⁵¹K was measured for the first time, and the precision of the ^51,52Ca mass values were improved significantly. The new mass values show a dramatic increase of the binding energy compared to those reported in the atomic mass evaluation. In particular, ⁵²Ca is more bound by 1.74 MeV, and the behavior with neutron number deviates substantially from the tabulated values. An increased binding was predicted recently based on calculations that include three-nucleon (3N) forces. We present a comparison to improved calculations, which agree remarkably with the evolution of masses with neutron number, making neutron-rich calcium isotopes an exciting region to probe 3N force

TITAN (TRIUMF's Ion Traps for Atomic and Nuclear science) is an online facility designed to carry out high-precision mass measurements on singly and highly charged radioactive ions. The TITAN Penning trap has been built and optimized in order to perform such measurements with an accuracy in the sub ppb-range. A detailed characterization of the TITAN Penning trap is presented and a new compensation method is derived and demonstrated, verifying the performance in the range of sub-ppb.