Core–shell structured BaTiO3@carbon hybrid particles fabricated via chemical vapor deposition can remarkably enhance the dielectric performance of polymer composites.
ARTICLE
This journal isUpward self-polarization phenomenon was observed and studied in the highly (001)-oriented BaTiO 3 /LaNiO 3 polycrystalline film, and the polycrystalline film was in situ prepared by radio frequency magnetron sputtering at 400°C without post treatment. The low temperature crystallization and high orientation of BaTiO 3 polycrystalline film may be caused by the better compatibility between BaTiO 3 and LaNiO 3 . The upward self-polarization phenomena was characterized by piezoelectric force microscopy (PFM), and the coupling effects of low crystallization temperature, high (001) orientation, large compressive strain gradient and preferred orientation of defect dipoles are considered to be responsible for the upward self-polarization phenomena in the BaTiO 3 /LaNiO 3 polycrystalline film during the cooling process, especially when ferroelectric domains nucleate and grow near 120°C.
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