Abstract. Impurities control a variety of physical properties of polar ice. Their impact can be observed at all scalesfrom the microstructure (e.g., grain size and orientation) to the ice sheet flow behavior (e.g., borehole tilting and closure). Most impurities in ice form micrometer-sized inclusions. It has been suggested that these µ inclusions control the grain size of polycrystalline ice by pinning of grain boundaries (Zener pinning), which should be reflected in their distribution with respect to the grain boundary network. We used an optical microscope to generate high-resolution large-scale maps (3 µm pix −1 , 8×2 cm 2 ) of the distribution of micro-inclusions in four polar ice samples: two from Antarctica (EDML, MIS 5.5) and two from Greenland (NEEM, Holocene). The in situ positions of more than 5000 µ inclusions have been determined. A Raman microscope was used to confirm the extrinsic nature of a sample proportion of the mapped inclusions. A superposition of the 2-D grain boundary network and µ-inclusion distributions shows no significant correlations between grain boundaries and µ inclusions. In particular, no signs of grain boundaries harvesting µ inclusions could be found and no evidence of µ inclusions inhibiting grain boundary migration by slow-mode pinning could be detected. Consequences for our understanding of the impurity effect on ice microstructure and rheology are discussed.

Insoluble and soluble impurities, enclosed in polar ice sheets, have a major impact on the deformation behaviour of the ice. Macro- and Micro-scale deformation observed in ice sheets and ice cores has been retraced to chemical loads in the ice, even though the absolute concentration is negligible. And therefore the exact location of the impurities matters: Allocating impurities to specific locations inside the ice microstructure inherently determines the physical explanation of the observed interaction between chemical load and the deformational behaviour. Both, soluble and non-soluble impurities were located in grain boundaries, triple junctions or in the grain interior, using different methods, samples and theoretical approaches. While each of the observations is adding to the growing understanding of the effect of impurities in polar ice, the growing number of ambiguous results calls for a dedicated and holistic approach in assessing the findings. Thus, we here aim to give a state of the art overview of the development in microstructural impurity research over the last 20 years. We evaluate the used methods, discuss proposed deformation mechanisms and identify two main reasons for the observed ambiguity: 1) limitations and biases of measurement techniques and 2) the physical state of the analysed impurity. To overcome these obstacles we suggest possible approaches, such as the continuous analysis of impurities in deep ice cores with complementary methods, the implementation of these analyses into established in-situ ice core processing routines, a more holistic analysis of the microstructural location of impurities, and an enhanced knowledge-transfer via an open access data base.

Abstract. The crystal orientation fabric (COF) of a polar ice sheet has a significant effect on the rheology of the ice sheet. With the aim of better understanding the deformation regime of ice sheets, the work presented here investigates the COF in the upper 80 % of the Dome Fuji Station ice core in East Antarctica. Dielectric anisotropy (Δε) data were acquired as a novel indicator of the vertical clustering of COF resulting from vertical compressional strain within the dome. The Δε values were found to exhibit a general increase with depth, but with fluctuations over distances in the order of 10–102 m. In addition, significant decreases in Δε were found to be associated with depths corresponding to three major glacial to interglacial transitions. These changes in Δε are ascribed to variations in the deformational history caused by dislocation motion occurring from near-surface depths to deeper layers. Fluctuations in Δε over distances of less than 0.5 m exhibited a strong inverse correlation with Δε at depths greater than approximately 1200 m, indicating that they were enhanced during the glacial-interglacial transitions. The Δε data also exhibited a positive correlation with the concentration of chloride ions and an inverse correlation with the amount of dust particles in the ice core at greater depths corresponding to decreases in the degree of c axis clustering. Finally, we found that fluctuations in Δε persisted to approximately 80 % of the total depth of the ice sheet. These data suggest that the factors determining the deformation of ice include the concentration of chloride ions and the amount of dust particles, and that the layered contrast associated with the COF is preserved all the way from the near-surface to a depth corresponding to approximately 80 % of the thickness of the ice sheet. These findings provide important implications regarding further development of the COF under the various stress-strain configurations that the ice will experience in the deepest region, approximately 20 % of the total depth from the ice/bed interface.