The emerging heterogeneous membranes show unprecedented superiority in harvesting the osmotic energy between ionic solutions of different salinity. However, the power densities are limited by the low interfacial transport efficiency caused by a mismatch of pore alignment and insufficient coupling between channels of different dimensions. Here we demonstrate the use of three-dimensional (3D) gel interface to achieve high-performance osmotic energy conversion through hybridizing polyelectrolyte hydrogel and aramid nanofiber membrane. The ionic diode effect of the heterogeneous membrane facilitates one-way ion diffusion, and the gel layer provides a charged 3D transport network, greatly enhancing the interfacial transport efficiency. When used for harvesting the osmotic energy from the mixing of sea and river water, the heterogeneous membrane outperforms the state-of-the-art membranes, to the best of our knowledge, with power densities of 5.06 W m −2. The diversity of the polyelectrolyte and gel makes our strategy a potentially universal approach for osmotic energy conversion.

As an approach to harvesting sustainable energy from ambient conditions, the osmotic energy between river water and seawater contributes to solving global issues such as the energy shortage and environmental pollution. Current attempts based on a reverse electrodialysis technique are limited mainly due to the economically unviable power density and inadequate mass transportation of membrane materials. Here, we demonstrate a benign strategy for designing a multilayer graphene oxide-silk nanofiber-graphene oxide biomimetic nacre-like sandwich as an osmotic power generator. Enhanced interfacial bonding endows the composite membranes with long-term stability in saline, and meanwhile, the two-dimensional nanofluidic channel configuration also reduces the ion transport resistance and provides large storage spaces for ions. Thus, the output power density of the proposed membrane-based generator achieves a value of up to 5.07 W m −2 by mixing seawater and river water. Furthermore, we experimentally and theoretically demonstrate that the thermal-field drives the increased output power density due to the advances in ionic movement range and activity of electrode reaction, showing the promise of strengthened thermo-osmotic energy conversion.

As an emerging potential energy source to address the energy crisis, osmotic energy has attracted increasing attention. Fast ion transport is essential for this blue energy and for other membrane-based...