Solar‐thermal water evaporation, as a promising method for clean water production, has attracted increasing attention. However, solar water evaporators that exhibit both high water vapor generation ability and anti‐oil‐fouling ability have not been reported. Here, a unique metal–organic‐framework‐based hierarchical structure, referred to as MOF‐based hierarchical structure (MHS), is rationally designed and prepared, which simultaneously displays a high solar absorption and a superhydrophilic and underwater superoleophobic surface property. As a proof‐of‐concept application, a device prepared from the MHS can achieve a high solar‐thermal water evaporation rate of 1.50 kg m−2 h−1 under 1 sun illumination. Importantly, the MHS also possesses an excellent anti‐oil‐fouling property, ensuring its superior water evaporation performance even in oil‐contaminated water. The high solar‐thermal water evaporation rate and anti‐oil‐fouling property make the MHS a promising material for the solar‐thermal water production.
Ion channels are essential for the regulation of neuronal functions. The significance of plasma membrane, mitochondrial, endoplasmic reticulum, and lysosomal ion channels in the regulation of Ca2+ is well established. In contrast, surprisingly less is known about the function of ion channels on the nuclear envelope (NE). Here we demonstrate the presence of functional large-conductance, calcium-activated potassium channels (BK channels) on the NE of rodent hippocampal neurons. Functionally blockade of nuclear BK channels (nBK channels) induces NE-derived Ca2+ release, nucleoplasmic Ca2+ elevation, and cAMP response element binding protein (CREB)-dependent transcription. More importantly, blockade of nBK channels regulates nuclear Ca2+-sensitive gene expression and promotes dendritic arborization in a nuclear Ca2+-dependent manner. These results suggest that nBK channel functions as a molecular linker between neuronal activity and nuclear Ca2+ to convey the signals from synapse to nucleus and is a new modulator for synaptic activity-dependent neuronal functions at the NE level.
Heterostructures consisting of distinct components have attracted considerable attention due to their unique properties and promising applications in catalysis enabled by the synergistic effect among different components. [1][2][3][4][5] Since phase engineering of nanomaterials (PEN) provides various strategies to rationally design and synthesize nanomaterials with novel crystal phases, [6] the delicate modu lation of crystal phases of each component in heterostructures with diverse morpho logies becomes possible, which is of great importance to realize tunable physical and chemical properties and enhanced perfor mances. In addition to controlling their compositions, morphologies, architec tures, facets, sizes, and dimensionalities, tremendous efforts have been devoted to constructing heterostructures con sisting of different phases during recent years. For example, highly luminescent CdSe/CdS heterostructure with tetrapod Phase engineering of nanomaterials (PEN) offers a promising route to rationally tune the physicochemical properties of nanomaterials and further enhance their performance in various applications. However, it remains a great challenge to construct well-defined crystalline@amorphous core-shell heterostructured nanomaterials with the same chemical components. Herein, the synthesis of binary (Pd-P) crystalline@amorphous heterostructured nanoplates using Cu 3−χ P nanoplates as templates, via cation exchange, is reported. The obtained nanoplate possesses a crystalline core and an amorphous shell with the same elemental components, referred to as c-Pd-P@a-Pd-P. Moreover, the obtained c-Pd-P@a-Pd-P nanoplates can serve as templates to be further alloyed with Ni, forming ternary (Pd-Ni-P) crystalline@amorphous heterostructured nanoplates, referred to as c-Pd-Ni-P@a-Pd-Ni-P. The atomic content of Ni in the c-Pd-Ni-P@a-Pd-Ni-P nanoplates can be tuned in the range from 9.47 to 38.61 at%. When used as a catalyst, the c-Pd-Ni-P@a-Pd-Ni-P nanoplates with 9.47 at% Ni exhibit excellent electrocatalytic activity toward ethanol oxidation, showing a high mass current density up to 3.05 A mg Pd −1 , which is 4.5 times that of the commercial Pd/C catalyst (0.68 A mg Pd −1 ).
Highlights d Chronic spike blockade with tetrodotoxin causes homeostatic spike broadening d Alternative splicing of BK channels by exclusion of a specific exon is responsible d Synaptic homeostasis starts CaM kinase signaling to drive nuclear exit of Nova-2 d Chronic inactivity and hyperactivity can initiate similar LTPlike events
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