The center-flavor symmetry of a gauge theory specifies the global form of consistent gauge and flavor bundle background field configurations. For 6d gauge theories which arise from a tensor branch deformation of a superconformal field theory (SCFT), we determine the global structure of such background field configurations, including possible continuous Abelian symmetry and R-symmetry bundles. Proceeding to the conformal fixed point, this provides a prescription for reading off the global form of the continuous factors of the zeroform symmetry, including possible non-trivial mixing between flavor and R-symmetry. As an application, we show that this global structure leads to a large class of 4d N = 2 SCFTs obtained by compactifying on a T 2 in the presence of a topologically non-trivial flat flavor bundle characterized by a 't Hooft magnetic flux. The resulting "Stiefel-Whitney twisted" compactifications realize several new infinite families of 4d N = 2 SCFTs, and also furnish a 6d origin for a number of recently discovered rank one and two 4d N = 2 SCFTs.