1,2,4-Triazole complexes. IX. The structure of tris-μ-(4-phenyl-1,2,4-triazole-N1,N2)-bis[bis(isothiocyanato)(4-phenyl-1,2,4-triazole-N1)cobalt(II)] hydrate, Co2(C8H7N3)5(NCS)4.xH2O (x≃2.7)

A Novel Mixed Ligand Dinuclear Complex of Cobalt (II): Synthesis, Characterization and Magnetic Studies

“…The complex crystallizes in the orthorhombic system with space group P2 1 Table 2) are comparable to previously reported values [22] .The Co-Co separation of 3.80546(5) Å is consistent with the value reported for a similar dinuclear Co (II) complex linked by μ-κ 2 N 1 , N 2 -1,2,4-triazole bridges [23]. The cobalt atom is positioned in a highly distorted octahedron where the angles subtended at the cobalt atom vary from 87.25˚ to 177.65˚.…”

Magnetic and Spectroscopic Properties of Metal(II) Thiocyanate Compounds with 3,4-Dialkyl Substituted 1,2,4-TriazoIes

“…Using 4-R-l,2,4-triazole (R = methyl, ethyl, allyl and phenyl) dinuclear compounds have been reported [3,8,20,21]; the same structure is proposed for the compounds reported now. The magnitude of the metal -metal interactions lie in the same range as observed for the compounds with symmetric triazoles, which in retrospect could be expected from the great similarity between the compounds.…”

“…The high g value for [Co 2 (mtbtz) 5 (NCS) 4 ](H 2 0) might indicate that this compound is not a pure Ising system. Engelfriet et al [20,21] have reported dinuclear compounds with the same composition using the ligands 4-phenyl-l,2,4-triazole and 4-methyl-l,2,4-triazole. It seems likely, that the now described compounds have the same overall structure, i.e.…”

Pt(II) complexes of 4-amino-4H-1,2,4-triazole

“…Coordination of I with Pt(II), elucidated by IR spectroscopy shows that the ligand is monodentate through the N-heterocyclic nitrogen, in accord with the electronic spectra as well as with the data of other metal complexes with the triazole derivatives, whose structures have been obtained by single crystal X-ray diffraction [39,40,[42][43][44][45][46]. The IR spectra of 1-3 are given in ''Supplementary material.''…”