2024
DOI: 10.1021/acs.joc.4c00296
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1,2-Difunctionalization of Aryne with Sulfenamide and Organohalide: Mild and Metal-Free Access to S-(o-Halo)aryl Sulfilimine

Padma Priya V. R,
Antony Haritha Mercy A,
Natarajan K
et al.

Abstract: A mild and metal-free approach has been developed for 1,2-difunctionalization of aryne using sulfenamides as a nucleophile and a halogen source (CX 4 ) as an electrophile to synthesize S-(o-halo)aryl sulfilimines. The late-stage functionalizations of halide handles via Suzuki−Miyaura and Buchwald−Hartwig reactions exhibit the synthetic utilities of the products. The chemoselectivity, regioselectivity, rapidity, and use of economical CCl 4 are the advantages of this protocol.

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