“…The short photoluminescence lifetimes of the three polymers indicate a faster electron transfer rate to the surface, which should be favourable for the HER. 28,49,[53][54][55] As shown in Fig. 6b, TPDBDT NPs exhibited the smallest Nyquist radius, indicating that they had the highest quality of the interface among the three TPD-based polymers, which is in favour of charge transport at the NP interface.…”