Abstract:In the title hydrated molecular salt, C6H16N2
+·2PF6
−·2H2O, the complete 1,4-dimethylpiperazine-1,4-diium dication is generated by crystallographic inversion symmetry and both C—N bonds are in equatorial orientations. In the crystal, the components are linked by O—H⋯F and N—H⋯O hydrogen bonds but there are no direct links between cations and anions.
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