1-Phenylpiperazine-1,4-diium tetrachloridocobalt(II)

Abstract

In the title mol­ecular salt, (C10H16N2)[CoCl4], the piperazine ring of the phenyl­piperazine dication adopts a chair conformation and the phenyl ring occupies an equatorial orientation. In the tetra­chlorido­cobaltate(II) dianion, the Co—Cl bond lengths for the chloride ions not accepting hydrogen bonds are significantly shorter than those for the chloride ions accepting such bonds. In the crystal, the components are linked by N—H⋯Cl hydrogen bonds, generating [001] chains.

Crystal structure of bis(2-amino-5-chloropyridinium) tetrachloridocobaltate(II)

“…In the [CoCl 4 ] 2À anion, the Co-Cl bond lengths range from 2.2645 (12) to 2.2934 (12) Å and the Cl-Co-Cl angles range from 104.84 (5) to 118.58 (5) , revealing considerable distortions from the ideal tetrahedral geometry. These values are in agreement with those observed in similar compounds (Dhieb et al, 2014;Mghandef & Boughzala, 2014;Oh et al, 2011). The different Co-Cl bond lengths in the [CoCl 4 ] 2À anion are related to the number of hydrogen bonds accepted by the Cl atoms.…”

Crystal structure studies of 4-ethylpiperazin-1-ium 3,5-dinitrobenzoate, 4-methylpiperazin-1-ium 3,5-dinitrobenzoate and 4-methylpiperazin-1-ium 4-iodobenzoate

“…It is also used in the synthesis of dyes, agrochemicals and other pharmaceutical compounds. The crystal structures of compounds derived from 1-ethylpiperazine, viz., chlorobis- (2-chlorobenzyl)(4-ethylpiperazine-1-dithiocarbamato-2 S,S 0 )tin(IV) (Li & Li, 2007), 1-diphenylmethyl-4-ethylpiperazine-1,4-diium dichloride (Qiao et al, 2010), (S)-3chloro-4-(4-ethylpiperazin-1-yl)-5-[(1R,2S,5R)-2-isopropyl-5methylcyclohexyloxy]furan-2(5H)-one (Fu et al, 2010), 4-{[5-(4-chlorophenyl)-1-(4-fluorophenyl)-1H-pyrazol-3-yl]carbon-yl}-N-ethylpiperazine-1-carboxamide (Shahani et al, 2011), 2-[4-(2-methoxyphenyl)piperazin-1-yl]-N-(pyridin-2-yl)acetamide (Lu & Jiang, 2011), N-(4-chlorophenyl)-4-ethylpiperazine-1-carboxamide (Li, 2011) and trichlorido(1ethylpiperazin-1-ium)cobalt(II) (Dhieb et al, 2014) have been reported.…”

Synthesis, structural characterization, antibacterial activity, DFT computational studies and thermal analysis of two new thiocyanate compounds based on 1-phenylpiperazine

“…The formation of complexes between organic molecules and cobalt-isothiocyanate moieties is especially important for their use in diverse fields of technological applications [24,25]. In view of the importance of piperazines the structural chemistry of various compounds that include piperazine and its derivatives does not cease to develop and continues to be a subject of research in many laboratories [26][27][28][29][30][31][32][33][34][35][36]. Piperazine and its derivatives have plentiful potential applications and are important ligands for constructing coordination complexes.…”