Abstract:The benzimidazolone part of the title molecule, C10H8N2O, is almost planar [r.m.s. deviation = 0.014 (1) Å] and the NCH2C CH group forms a dihedral angle of 67.95 (6)° with its best plane. In the crystal, molecules form inversion dimers via pairs of N—H⋯O hydrogen bonds. C—H⋯O interactions connect the dimers, forming a two-dimensional polymeric network parallel to (100).
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