We report results on the growth of Hg~_~Cd=Te native oxides using ultraviolet radiation. This method provides a dry, clean, low-temperature process for growing native oxides on Hg~ xCdxTe. Measurements of the stoichiometry and thicknesses of these oxides are presented and possible growth mechanisms discussed. The stoichiometry of the oxide/Hg~_~CdxTe interface after annealing is examined with regard to the encapsulation properties of these layers. Preliminary results obtained for high-temperature photochemical oxidation are also reported.Successful fabrication of Hgl_=CdxTe infrared detector arrays requires passivation of the Hg~_=Cd=Te surface. Consequently, the growth of native oxides on Hgl-xCd=Te is of considerable importance for this technology, especially when the electrical properties are strongly influenced by surface states and/or recombination velocities. Native oxides are generally used to passivate and stabilize surfaces so that the electrical performance of devices do not change during storage or operation (1). Also, as reported earlier (2, 3), photochemically grown native oxides are useful as an encapsulant for the annealing of Hgl-=CdxTe.Although anodic oxidation is probably the most common oxidation technique used for passivating Hgl_=Cd=Te surfaces in use (1), photochemically grown native oxides of Hgl_=Cd=Te exist which result in relative low fixed charge (Nf~ = 101~ cm -2) and fast interface state (Nss = 10 l~ cm -2 eV -1) densities (4). Photochemical oxidation in this work means that the Hgl_=Cd=Te surface is exposed to ultraviolet radiation (from a low-pressure mercury ]amp) in an 02 or N20 ambient. The UV generates electronically excited oxygen atoms as the oxidizing agent for forming the native oxide layer. A fundamental understanding of the stoichiometry, growth mechanisms, and interface properties of photochemically grown oxides is therefore of interest from both a technological and scientific point of view.Studies of the stoichiometry of photochemical oxides have been previously .reported using x-ray photoelectron spectroscopy (XPS) (5-7). However, preferential sputtering, an effect often observed in XPS measurements, causes difficulty in accurately determining the oxide composition, especially the Hg content. In order to more accurately determine the stoichiometry and other properties of these oxides, further investigation using complementary measurement techniques is needed. In this work, we evaluate the film stoichiometry using high depth resolution Rutherford backscattering (RBS) and Auger electron spectroscopy (AES). The oxide stoichiometry and major photochemical reactions are studied and discussed. Also, the encapsulation properties of this oxide for annealing are evaluated.