11H‐Isoindolo[2,1‐a]benzimidazoles

Lyaskovskyy, Volodymyr; Voitenko, Zoia; Ковтуненко, В. А.

doi:10.1002/chin.200746221

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2020

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“…Chemical reduction of the imido complexes afforded dicopper iminyl products as determined by EPR, Cu/N XAS, crystallography, and computations. The iminyl ligand is distinct from previously reported subvalent nitrogen motifs which arise from radical delocalization following nitride, 69,70 imide, 31,44,45,71 or amide [72][73][74][75] oxidation. 72,76 The iminyl complexes reported herein show modest disruption of the aryl units, arising from population of the NAr lowest-lying π* orbital.…”

Section: Discussionmentioning

confidence: 57%

Electronic Structures and Reactivity Profiles of Aryl Nitrenoid-Bridged Dicopper Complexes

et al. 2020

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Dicopper complexes templated by dinucleating, pacman dipyrrin ligand scaffolds ( Mes dmx, tBu dmx: dimethylxan-thine-bridged, cofacial bis-dipyrrin) were synthesized by deprotonation/ metalation with mesitylcopper (CuMes; Mes: mesityl) or by transmetalation with cuprous precursors from the corresponding deprotonated ligand. Neutral imide complexes ( R dmx)Cu 2 (μ 2 -NAr) (R: Mes, t Bu; Ar: 4-MeOC 6 H 4 , 3,5-(F 3 C) 2 C 6 H 3 ) were synthesized by treatment of the corresponding dicuprous complexes with aryl azides. While one-electron reduction of

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