2020
DOI: 10.1016/j.jallcom.2020.155185
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120 Years of nickel-based cathodes for alkaline batteries

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Cited by 29 publications
(27 citation statements)
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“…This is due to the incorporation of Co ions into Ni hydroxide layers preventing the mechanical failure that can be happen during the charging process due to the transformation of b-NiOOH to g-NiOOH. 20,29…”
Section: àmentioning
confidence: 99%
See 1 more Smart Citation
“…This is due to the incorporation of Co ions into Ni hydroxide layers preventing the mechanical failure that can be happen during the charging process due to the transformation of b-NiOOH to g-NiOOH. 20,29…”
Section: àmentioning
confidence: 99%
“…The rst approach is enhancing the stability of b-Ni(OH) 2 by arresting the formation of g-NiOOH from b-NiOOH by lowering the oxidation potential which prevents the overcharging of b-NiOOH to g-NiOOH. 20,29 The second approach is improving the stability of a-Ni(OH) 2 by inhibiting the transformation of g-NiOOH to b-Ni(OH) 2 during the discharge process. 15,23 On the other hand, the co-existence of Co into Ni(OH) 2 crystal lattice changes the morphology of electrode material that results in reinforcing the kinetics of the electrode.…”
Section: Introductionmentioning
confidence: 99%
“…With a history of more than 120 years of rechargeable alkaline batteries, Ni­(OH) 2 /NiOOH is considered to be the key redox couple owing to its good reversibility, high redox potential, adequate theoretical capacity, abundance, low toxicity, and cost effectiveness . In general, Ni­(OH) 2 has two polymorphic forms, α-Ni­(OH) 2 and β-Ni­(OH) 2 (Figure c), and the latter is widely used as cathode material, exhibiting higher thermodynamic stability in alkaline solution than its α counterpart .…”
Section: Introductionmentioning
confidence: 99%
“…(c) Schematic of reaction mechanisms and structures of nickel hydroxides. Reproduced with permission from ref . Copyright 2020 Elsevier.…”
Section: Introductionmentioning
confidence: 99%
“…Various battery chemistries have been introduced over the last three decades, each with its own unique specific energy, capacity, operating life and maintenance costs [11][12][13]. As a result, it is common practice to compare several cell chemistries for application-specific implementations in order to achieve the greatest techno-economic viability [14,15].…”
Section: Introductionmentioning
confidence: 99%