14-Benzoylmesaconine hydrochloride methanol monosolvate

Abstract

The title compound, C31H44N3O10 +·Cl−·CH4O, is the methanol solvate of 8-benzo­yloxy-,9,11,11a-tetra­hydroxy-6,10,13-trimeth­oxy-3-meth­oxy­methyl-1-methyl­tetra­deca­hydro-1H-3,6a,12-(epiethane-1,1,2-tri­yl)-7,9-methanona­phtho[2,3-b]azocin-1-ium chloride, the amine-protonated hydro­chloride of 14-benzoyl­mesaconine hydro­chloride. The cation has an aconitine carbon skeleton with four six-membered rings of which three display chair conformations and one a boat conformation, and two five-membered rings with envelope conformations. In the crystal, the components are connected into an infinite chain by inter- and intra­molecular O—H⋯O, N—H⋯O and O—H⋯Cl hydrogen bonds.