A breakthrough for non-fullerene acceptors (NFAs) is
their efficient
photocharge generation and low nonradiative voltage loss (ΔV
nrad) in a condition of negligible energy offset
(ΔG
S1,CT) between the lowest singlet
state (S1) and the relaxed charge transfer (CT) state.
This inspires the idea of viewing the donor/acceptor (D/A) binary
blend as a single component in organic solar cells (OSCs) and attracts
tremendous studies on the D/A pairs with negligible ΔG
S1,CT. Unfortunately, an arbitrarily chosen
material combination usually results in severe photovoltaic performance
loss. To solve this problem, we present a diffused heterojunction
(DHJ) doping strategy at the D/A heterojunction with small ΔG
S1,CT. The electronic doping alleviates the
performance loss by accelerating the exciton dissociation rate and
reducing the ΔV
nrad. After examining
the DHJ doping strategy in other six NFA material combinations, we
are confident to point out that our work opens an avenue for pursuing
intrinsic high OSC performance comparing with other single-component
photovoltaic technologies.