2019
DOI: 10.1002/slct.201903545
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1D Core‐shell MnO@S, N co‐Doped Carbon for High Performance Lithium Ion Battery Anodes

Abstract: Manganese monoxide (MnO) is a promising anode material for lithium ion batteries, but it often shows poor electrochemical performance due to some inevitable drawbacks including intrinsic low electrical conductivity, poor stability, and severe polarization. In this work, a 1D core‐shell MnO@S, N co‐doped carbon material (MnO@SNC) was obtained by pyrolysis of MnO2@PPy precursor at 600 °C in N2 atmosphere. When evaluated as an anode for lithium ion batteries, the unique structure and composition advantages endow … Show more

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Cited by 6 publications
(1 citation statement)
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“…The comparison of capacity and cycle stability for Co/MnO@C composite nanofibers and other metallic oxide-based materials is listed in Table . , We can clearly observe that our materials have superior electrochemical performance compared to other similar types of complex materials. Such excellent rate capability and cycle stability can be ascribed to the following reasons: (1) the nanofibers have a large surface area and structural voids and were advantageous to the transport of Li ions between the electrolyte and active substance, (2) the carbon which was coated on the surface of nanofibers can prevent the fall of the broken metallic oxide, thus improving the cycle stability of the electrode, (3) the metal Co which was reduced by the carbon can be an effective catalyst for improving the reversibility of the SEI films.…”
Section: Resultsmentioning
confidence: 83%
“…The comparison of capacity and cycle stability for Co/MnO@C composite nanofibers and other metallic oxide-based materials is listed in Table . , We can clearly observe that our materials have superior electrochemical performance compared to other similar types of complex materials. Such excellent rate capability and cycle stability can be ascribed to the following reasons: (1) the nanofibers have a large surface area and structural voids and were advantageous to the transport of Li ions between the electrolyte and active substance, (2) the carbon which was coated on the surface of nanofibers can prevent the fall of the broken metallic oxide, thus improving the cycle stability of the electrode, (3) the metal Co which was reduced by the carbon can be an effective catalyst for improving the reversibility of the SEI films.…”
Section: Resultsmentioning
confidence: 83%