2,2,6,6-Tetramethylpiperidinium pentachlorobenzenethiolate

Abstract

Katarzyna Baranowska and Natalia Piwowarska S1. Comment The crystal structure of the title compound shows an asymmetric unit consisting of one pentachlorobenzenethiolate anion and one 2,2,6,6-tetramethylpiperidinium cation. The ammonium thiolate forms a dimer [C 6 Cl 5 S (-) H 2 N (+) C 5 H 6 Me 4 ] 2 (Fig.

2,2,6,6-Tetramethylpiperidinium triisopropoxysilanethiolate

“…The aggregates contain eight-membered ring built due to the formation of four charge-assisted (+) (-) hydrogen bonds (graph theory motif R 2 4 (8) according to Etter, 1990;Bernstein et al, 1995). The N•••S distances (Table 1) lie in the range comparable with the values observed in aromatic thiolates (Baranowska & Piwowarska, 2008) or silanethiolates (Baranowska, Chojnacki, Gosiewska, Wojnowski, 2006).…”

“…For the structures of similar compounds and comparison of bond distances, see Baranowska, Chojnacki, Gosiewska & Wojnowski (2006); Baranowska, Chojnacki, Konitz et al (2006); Baranowska & Piwowarska (2008); Becker et al (2004). For the graph-set description of hydrogen-bonding patterns, see Bernstein et al (1995); Etter (1990).…”

Charge-assisted N(+)–H···(−)S hydrogen bonds in the crystal structure of selected diammonium thiophenolates

“…Application of primary amines leads to tetrameric salts with a core bound by a 'cubane-like' hydrogen bonding net [26]. Secondary amines give derivatives with discrete dimeric units in the solid state [27][28][29]. So we have finite, 'point type' or zero-dimensional hydrogen bonds that cannot create crystal-wide web in both cases.…”