The title compound, C18H12N6O6, was prepared from the reaction of 4-(phenyldiazenyl)aniline (aniline yellow) with picrylsulfonic acid. The dihedral angle formed by the two benzene rings of the diphenyldiazenyl ring system is 6.55 (13)° and that formed by the rings of the picrate–aniline ring system is 48.76 (12)°. The molecule contains an intramolecular aniline–nitro N—H⋯O hydrogen bond.