2,6-Bis(2-chloroethyl)-8b,8c-diphenylperhydro-2,3a,4a,6,7a,8a-hexaazacyclopenta[<i>def</i>]fluorene-4,8-dithione

The title compound, C36H34N4O4S2, is a thioglycoluril derivative, which bears two phenyl substituents on its convex face and two methoxy substituted o-xylylenes as sidewalls of the molecular clip. There is one half-molecule in the asymmetric unit: a crystallographic twofold axis generates the complete molecule. The non-planar seven-membered rings adopt chair conformations, while the two five-membered rings exhibit envelope conformations and make a dihedral angle of 68.46 (12)°. The O atoms of the methoxy groups are coplanar with the six-membered o-xylylene sidewalls.

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

2,6-Bis(2-chloroethyl)-8b,8c-diphenylperhydro-2,3a,4a,6,7a,8a-hexaazacyclopenta[def]fluorene-4,8-dithione

Abstract: In the title molecule, C24H26Cl2N6S2, the two phenyl rings form a dihedral angle of 51.95 (7)° and the distance between their centroids is 4.156 (8) Å. The crystal packing exhibits weak intermolecular C—H⋯S and C—H⋯N hydrogen bonds.

Cited by 4 publications

References 4 publications

Glycolurils in the synthesis of fused polyheterocyclic compounds

Glycolurils in the synthesis of fused polyheterocyclic compounds

New cage-fused polyaza polycyclic systems based on thioglycolurils and alkanediamines

3,6,14,17-Tetramethoxy-22,23-diphenyl-1,10,12,21-tetraazahexacyclo[19.2.1.0^2,7.0^10,23.0^12,22.0^13,18]tetracosa-2(7),3,5,13(18),14,16-hexaene-11,24-dithione

Contact Info

Product

Resources

About

2,6-Bis(2-chloroethyl)-8b,8c-diphenylperhydro-2,3a,4a,6,7a,8a-hexaazacyclopenta[def]fluorene-4,8-dithione

Abstract: In the title mol­ecule, C24H26Cl2N6S2, the two phenyl rings form a dihedral angle of 51.95 (7)° and the distance between their centroids is 4.156 (8) Å. The crystal packing exhibits weak inter­molecular C—H⋯S and C—H⋯N hydrogen bonds.

Cited by 4 publications

References 4 publications

Glycolurils in the synthesis of fused polyheterocyclic compounds

Glycolurils in the synthesis of fused polyheterocyclic compounds

New cage-fused polyaza polycyclic systems based on thioglycolurils and alkanediamines

3,6,14,17-Tetramethoxy-22,23-diphenyl-1,10,12,21-tetraazahexacyclo[19.2.1.02,7.010,23.012,22.013,18]tetracosa-2(7),3,5,13(18),14,16-hexaene-11,24-dithione

Contact Info

Product

Resources

About

Abstract: In the title molecule, C24H26Cl2N6S2, the two phenyl rings form a dihedral angle of 51.95 (7)° and the distance between their centroids is 4.156 (8) Å. The crystal packing exhibits weak intermolecular C—H⋯S and C—H⋯N hydrogen bonds.

3,6,14,17-Tetramethoxy-22,23-diphenyl-1,10,12,21-tetraazahexacyclo[19.2.1.0^2,7.0^10,23.0^12,22.0^13,18]tetracosa-2(7),3,5,13(18),14,16-hexaene-11,24-dithione